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State the differences between Gaseous fuels and solid fuels. A gaseous fuel has the following composition: CH 4 = 38%, H 2 = 26%, N 2 = 6%, CO = 26% and CO 2 = 4%. Find the stoichiometric air/fuel ratio by volume.

Chemistry

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2. a) State the differences between Gaseous fuels and solid fuels.

  • Gaseous Fuels:
    • Easier to handle and transport (e.g., via pipelines).
    • Burn cleanly with minimal ash and particulate matter.
    • Combustion rate is easier to control.
    • Require specialized storage (e.g., pressurized tanks).
  • Solid Fuels:
    • Easier to store in bulk (e.g., piles).
    • Produce significant ash and particulate matter upon combustion.
    • Combustion rate is more challenging to control.
    • Transportation often requires heavy machinery.

2. b) A gaseous fuel has the following composition: CH4=38%CH_4 = 38\%, H2=26%H_2 = 26\%, N2=6%N_2 = 6\%, CO=26%CO = 26\% and CO2=4%CO_2 = 4\%. Find the stoichiometric air/fuel ratio by volume.

  1. Write the balanced combustion equations for each combustible component and determine the oxygen required.

    Assume 100 volumes of fuel.

    • For CH4CH_4 (38 volumes): CH4+2O2→CO2+2H2OCH_4 + 2O_2 \to CO_2 + 2H_2O Oxygen required: 38×2=7638 \times 2 = 76 volumes of O2O_2.
    • For H2H_2 (26 volumes): H2+12O2→H2OH_2 + \frac{1}{2}O_2 \to H_2O Oxygen required: 26×12=1326 \times \frac{1}{2} = 13 volumes of O2O_2.
    • For COCO (26 volumes): CO+12O2→CO2CO + \frac{1}{2}O_2 \to CO_2 Oxygen required: 26×12=1326 \times \frac{1}{2} = 13 volumes of O2O_2.
    • N2N_2 (6 volumes) and CO2CO_2 (4 volumes) are inert and do not require oxygen for combustion.
  2. Calculate the total oxygen required.

    Total oxygen required per 100 volumes of fuel = 76+13+13=10276 + 13 + 13 = 102 volumes of O2O_2.

  3. Calculate the volume of air required.

    Air is approximately 21% oxygen by volume.
    Volume of air required = Total oxygen requiredFraction of oxygen in air\frac{\text{Total oxygen required}}{\text{Fraction of oxygen in air}}

    Vair=102 volumes0.21≈485.71 volumes of airV_{air} = \frac{102 \text{ volumes}}{0.21} \approx 485.71 \text{ volumes of air}
  4. Calculate the stoichiometric air/fuel ratio by volume.

    Air/fuel ratio by volume = Volume of air requiredVolume of fuel\frac{\text{Volume of air required}}{\text{Volume of fuel}}

    Air/Fuel Ratio=485.71 volumes of air100 volumes of fuel≈4.857\text{Air/Fuel Ratio} = \frac{485.71 \text{ volumes of air}}{100 \text{ volumes of fuel}} \approx 4.857

    The stoichiometric air/fuel ratio by volume is 4.857\boxed{\text{4.857}}.

    3. a) State the steady flow energy equation.

    The Steady Flow Energy Equation (SFEE) for a single inlet and single outlet system is given by:

    Q˙−W˙=m˙[(h2−h1)+V22−V122+g(z2−z1)]\dot{Q} - \dot{W} = \dot{m} \left[ (h_2 - h_1) + \frac{V_2^2 - V_1^2}{2} + g(z_2 - z_1) \right]

    where:

    • Q˙\dot{Q} is the rate of heat transfer to the system.
    • W˙\dot{W} is the rate of work done by the system.
    • m˙\dot{m} is the mass flow rate.
    • hh is the specific enthalpy (h=u+Pvh = u + Pv).
    • VV is the velocity.
    • gg is the acceleration due to gravity.
    • zz is the elevation.
    • Subscripts 1 and 2 denote inlet and outlet conditions, respectively.

    3. b) In a steady flow system, a substance flows at a rate of 5.2 kg/sec5.2 \text{ kg/sec}. It enters at a pressure of 620 kN/m2620 \text{ kN/m}^2, a velocity of 298 m/sec298 \text{ m/sec}, internal energy 2100 kJ/kg2100 \text{ kJ/kg}, and specific volume 0.37 m3/kg0.37 \text{ m}^3\text{/kg}. It leaves at a pressure of 130 kN/m2130 \text{ kN/m}^2, a velocity of 145 m/sec145 \text{ m/sec}, internal energy 1500 kJ/kg1500 \text{ kJ/kg}, and specific volume 1.2 m3/kg1.2 \text{ m}^3\text{/kg}. During its passage through the system, the substance rejects 120 kJ/sec120 \text{ kJ/sec} of heat. Determine the work done per kg of the substance.

    Given data:

    • Mass flow rate m˙=5.2 kg/s\dot{m} = 5.2 \text{ kg/s}
    • Inlet (State 1): P1=620 kPaP_1 = 620 \text{ kPa}, V1=298 m/sV_1 = 298 \text{ m/s}, u1=2100 kJ/kgu_1 = 2100 \text{ kJ/kg}, v1=0.37 m3/kgv_1 = 0.37 \text{ m}^3\text{/kg}
    • Exit (State 2): P2=130 kPaP_2 = 130 \text{ kPa}, V2=145 m/sV_2 = 145 \text{ m/s}, u2=1500 kJ/kgu_2 = 1500 \text{ kJ/kg}, v2=1.2 m3/kgv_2 = 1.2 \text{ m}^3\text{/kg}
    • Heat rejected Q˙out=120 kJ/s\dot{Q}_{out} = 120 \text{ kJ/s}. Therefore, heat added to the system Q˙=−120 kJ/s\dot{Q} = -120 \text{ kJ/s}.
    • Assume negligible change in potential energy (g(z2−z1)=0g(z_2 - z_1) = 0).

    The SFEE per unit mass is:

    q−w=(h2−h1)+V22−V122q - w = (h_2 - h_1) + \frac{V_2^2 - V_1^2}{2}

    We need to find ww, the work done per kg. So, w=q−(h2−h1)−V22−V122w = q - (h_2 - h_1) - \frac{V_2^2 - V_1^2}{2}.

  5. Calculate the specific heat transfer qq.

    q=Q˙m˙=−120 kJ/s5.2 kg/s≈−23.0769 kJ/kgq = \frac{\dot{Q}}{\dot{m}} = \frac{-120 \text{ kJ/s}}{5.2 \text{ kg/s}} \approx -23.0769 \text{ kJ/kg}
  6. Calculate the specific enthalpy at the inlet (h1h_1) and outlet (h2h_2).

    Specific enthalpy h=u+Pvh = u + Pv.

    h1=u1+P1v1=2100 kJ/kg+(620 kPa×0.37 m3/kg)h_1 = u_1 + P_1 v_1 = 2100 \text{ kJ/kg} + (620 \text{ kPa} \times 0.37 \text{ m}^3\text{/kg}) h1=2100 kJ/kg+229.4 kJ/kg=2329.4 kJ/kgh_1 = 2100 \text{ kJ/kg} + 229.4 \text{ kJ/kg} = 2329.4 \text{ kJ/kg} h2=u2+P2v2=1500 kJ/kg+(130 kPa×1.2 m3/kg)h_2 = u_2 + P_2 v_2 = 1500 \text{ kJ/kg} + (130 \text{ kPa} \times 1.2 \text{ m}^3\text{/kg}) h2=1500 kJ/kg+156 kJ/kg=1656 kJ/kgh_2 = 1500 \text{ kJ/kg} + 156 \text{ kJ/kg} = 1656 \text{ kJ/kg}
  7. Calculate the change in specific enthalpy (h2−h1h_2 - h_1).

    h2−h1=1656 kJ/kg−2329.4 kJ/kg=−673.4 kJ/kgh_2 - h_1 = 1656 \text{ kJ/kg} - 2329.4 \text{ kJ/kg} = -673.4 \text{ kJ/kg}
  8. Calculate the change in kinetic energy.

    V22−V122=(145 m/s)2−(298 m/s)22\frac{V_2^2 - V_1^2}{2} = \frac{(145 \text{ m/s})^2 - (298 \text{ m/s})^2}{2} =21025 m2/s2−88804 m2/s22=−67779 m2/s22= \frac{21025 \text{ m}^2\text{/s}^2 - 88804 \text{ m}^2\text{/s}^2}{2} = \frac{-67779 \text{ m}^2\text{/s}^2}{2} =−33889.5 J/kg=−33.8895 kJ/kg= -33889.5 \text{ J/kg} = -33.8895 \text{ kJ/kg}
  9. Calculate the work done per kg (ww).

    w=q−(h2−h1)−V22−V122w = q - (h_2 - h_1) - \frac{V_2^2 - V_1^2}{2} w=−23.0769 kJ/kg−(−673.4 kJ/kg)−(−33.8895 kJ/kg)w = -23.0769 \text{ kJ/kg} - (-673.4 \text{ kJ/kg}) - (-33.8895 \text{ kJ/kg}) w=−23.0769+673.4+33.8895 kJ/kgw = -23.0769 + 673.4 + 33.8895 \text{ kJ/kg} w=684.2126 kJ/kgw = 684.2126 \text{ kJ/kg}

    The work done per kg of the substance is 684.21 kJ/kg\boxed{\text{684.21 kJ/kg}}.

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