Balance these redox reaction 1 I-T ClO-3 equal I-3 TCL 2 SO32- t Lui (OH) -3 equal Lui t SO2 4

Chemistry

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Answer

9I−+ClO3−+6H+→3I3−+Cl−+3H2O9I^- + ClO_3^- + 6H^+ \to 3I_3^- + Cl^- + 3H_2O

3SO32−+2Lu(OH)3→3SO42−+3H2O+2Lu3SO_3^{2-} + 2Lu(OH)_3 \to 3SO_4^{2-} + 3H_2O + 2Lu

Step-by-step solution

20 steps

Reaction 1: I−+ClO3−→I3−+Cl−I^- + ClO_3^- \to I_3^- + Cl^- (acidic medium)

  1. Identify oxidation and reduction half-reactions.

    Oxidation: 3I−→I3−3I^- \to I_3^-
    Reduction: ClO3−→Cl−ClO_3^- \to Cl^-

  2. Balance oxidation half-reaction for I.

    3I−→I3−3I^- \to I_3^- (already balanced)

  3. Balance charge in oxidation half-reaction.

    Left: charge −3-3, right: charge −1-1
    Add 2e−2e^- to right: 3I−→I3−+2e−3I^- \to I_3^- + 2e^-

  4. Balance reduction half-reaction for Cl.

    ClO3−→Cl−ClO_3^- \to Cl^-

  5. Balance O atoms with H2OH_2O.

    ClO3−→Cl−+3H2OClO_3^- \to Cl^- + 3H_2O

  6. Balance H atoms with H+H^+.

    ClO3−+6H+→Cl−+3H2OClO_3^- + 6H^+ \to Cl^- + 3H_2O

  7. Balance charge in reduction half-reaction.

    Left: charge (−1+6)=+5( -1 + 6 ) = +5, right: charge −1-1
    Add 6e−6e^- to left: ClO3−+6H++6e−→Cl−+3H2OClO_3^- + 6H^+ + 6e^- \to Cl^- + 3H_2O

  8. Equalize electrons (LCM of 2 and 6 is 6).

    Multiply oxidation by 3: 3(3I−→I3−+2e−)  ⟹  9I−→3I3−+6e−3(3I^- \to I_3^- + 2e^-) \implies 9I^- \to 3I_3^- + 6e^-
    Reduction: ClO3−+6H++6e−→Cl−+3H2OClO_3^- + 6H^+ + 6e^- \to Cl^- + 3H_2O

  9. Add half-reactions.

    9I−+ClO3−+6H++6e−→3I3−+Cl−+3H2O+6e−9I^- + ClO_3^- + 6H^+ + 6e^- \to 3I_3^- + Cl^- + 3H_2O + 6e^-
  10. Simplify (cancel 6e−6e^-).

    9I−+ClO3−+6H+→3I3−+Cl−+3H2O9I^- + ClO_3^- + 6H^+ \to 3I_3^- + Cl^- + 3H_2O

    \boxed{9I−+ClO3−+6H+→3I3−+Cl−+3H2O9I^- + ClO_3^- + 6H^+ \to 3I_3^- + Cl^- + 3H_2O}

    Reaction 2: SO32−+Lu(OH)3→Lu+SO42−SO_3^{2-} + Lu(OH)_3 \to Lu + SO_4^{2-} (basic medium)

  11. Identify oxidation and reduction half-reactions.

    Oxidation: SO32−→SO42−SO_3^{2-} \to SO_4^{2-}
    Reduction: Lu(OH)3→LuLu(OH)_3 \to Lu

  12. Balance oxidation half-reaction for S.

    SO32−→SO42−SO_3^{2-} \to SO_4^{2-}

  13. Balance O atoms with OH−OH^-.

    SO32−+2OH−→SO42−+H2OSO_3^{2-} + 2OH^- \to SO_4^{2-} + H_2O

  14. Balance charge in oxidation half-reaction.

    Left: charge (−2−2)=−4( -2 -2 ) = -4, right: charge (−2−0)=−2( -2 -0 ) = -2
    Add 2e−2e^- to right: SO32−+2OH−→SO42−+H2O+2e−SO_3^{2-} + 2OH^- \to SO_4^{2-} + H_2O + 2e^-

  15. Balance reduction half-reaction for Lu.

    Lu(OH)3→LuLu(OH)_3 \to Lu

  16. Balance O atoms with OH−OH^-.

    Lu(OH)3→Lu+3OH−Lu(OH)_3 \to Lu + 3OH^-

  17. Balance charge in reduction half-reaction.

    Left: charge −3-3, right: charge (0−3)=−3( 0 -3 ) = -3 (balanced for atoms, now electrons)
    Lu from +3 to 0, add 3e−3e^- to left: Lu(OH)3+3e−→Lu+3OH−Lu(OH)_3 + 3e^- \to Lu + 3OH^-

  18. Equalize electrons (LCM of 2 and 3 is 6).

    Multiply oxidation by 3: 3(SO32−+2OH−→SO42−+H2O+2e−)  ⟹  3SO32−+6OH−→3SO42−+3H2O+6e−3(SO_3^{2-} + 2OH^- \to SO_4^{2-} + H_2O + 2e^-) \implies 3SO_3^{2-} + 6OH^- \to 3SO_4^{2-} + 3H_2O + 6e^-
    Multiply reduction by 2: 2(Lu(OH)3+3e−→Lu+3OH−)  ⟹  2Lu(OH)3+6e−→2Lu+6OH−2(Lu(OH)_3 + 3e^- \to Lu + 3OH^-) \implies 2Lu(OH)_3 + 6e^- \to 2Lu + 6OH^-

  19. Add half-reactions.

    3SO32−+6OH−+2Lu(OH)3+6e−→3SO42−+3H2O+2Lu+6OH−+6e−3SO_3^{2-} + 6OH^- + 2Lu(OH)_3 + 6e^- \to 3SO_4^{2-} + 3H_2O + 2Lu + 6OH^- + 6e^-
  20. Simplify (cancel 6OH−6OH^- and 6e−6e^-).

    3SO32−+2Lu(OH)3→3SO42−+3H2O+2Lu3SO_3^{2-} + 2Lu(OH)_3 \to 3SO_4^{2-} + 3H_2O + 2Lu

    \boxed{3SO32−+2Lu(OH)3→3SO42−+3H2O+2Lu3SO_3^{2-} + 2Lu(OH)_3 \to 3SO_4^{2-} + 3H_2O + 2Lu}

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