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Write the balanced chemical equations for the reaction of sulfur(IV) oxide with sodium hydroxide, assuming sulfur(IV) oxide is in excess.

Chemistry

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  1. When sulfur(IV) oxide (SO2SO_2) is passed into a solution of sodium hydroxide (NaOHNaOH) for a long time, it means SO2SO_2 is in excess. Initially, SO2SO_2 reacts with NaOHNaOH to form sodium sulfite (Na2SO3Na_2SO_3): SO2(g)+2NaOH(aq)→Na2SO3(aq)+H2O(l)SO_2(g) + 2NaOH(aq) \rightarrow Na_2SO_3(aq) + H_2O(l) If SO2SO_2 continues to be passed, the excess SO2SO_2 reacts with the formed sodium sulfite and water to produce sodium hydrogen sulfite (also known as sodium bisulfite):
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