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Complete the diagram for electrical conduction in lead (II) iodide and explain observations and equations.

Chemistry

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  1. The diagram below shows an experiment for investigating electrical conduction in lead (II) iodide. Study it and answer the questions that follow:

    • iii) Complete the diagram by indicating the condition missing in the diagram but must be present for electrical conduction to take place. (1mk) The missing condition is heat. A Bunsen burner flame should be drawn under the boiling tube to melt the lead(II) iodide.

    • b) Why is it necessary to leave a gap between the cork and the boiling tube? (1mk) To allow for the escape of any fumes produced (e.g., iodine vapor) and to prevent pressure build-up inside the boiling tube as the contents are heated.

    • c) State two observations that are expected at the end of the experiment. (2mks)

      • i) The bulb will light up, indicating electrical conduction.
      • ii) A grey/silvery solid (lead metal) will be deposited at the cathode.
      • iii) Brown/purple fumes (iodine vapor) will be produced at the anode.
    • d) Write the equation taking place at:

      • Anode: 2I−(l)⟶I2(g)+2e−2\text{I}^{-}(\text{l}) \longrightarrow \text{I}_{2}(\text{g}) + 2\text{e}^{-}
      • Cathode: Pb2+(l)+2e−⟶Pb(s)\text{Pb}^{2+}(\text{l}) + 2\text{e}^{-} \longrightarrow \text{Pb}(\text{s})
    • e) Why should this experiment be carried out in a fume chamber? (1mk) Because iodine vapor produced at the anode is toxic and corrosive.

    • f) State two applications of electrolysis. (2mks)

      • i) Purification of metals (e.g., copper).
      • ii) Extraction of reactive metals from their ores (e.g., aluminium, sodium).
      • (Other valid answers include electroplating, anodizing, manufacture of chemicals like chlorine and sodium hydroxide).
  2. (The image shows a partially drawn structure of 2-methylhexane. Here is the complete structural formula with all hydrogen atoms shown.)

        H   H   H   H   H   H
        |   |   |   |   |   |
    H - C - C - C - C - C - C - H
        |   |   |   |   |   |
        H   C   H   H   H   H
            |
            H
            |
            H
    

    This represents 2-methylhexane.

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