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Describe the electrochemical process occurring in molten lead(II) bromide, including electrode identification, half-equations, and the function of an ammeter.

Chemistry

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Answer

b

Pb2+(l)+2e−⟶Pb(l)\text{Pb}^{2+}\text{(l)} + 2\text{e}^- \longrightarrow \text{Pb(l)}

2Br−(l)⟶Br2(g)+2e−2\text{Br}^{-}\text{(l)} \longrightarrow \text{Br}_2\text{(g)} + 2\text{e}^-

Step-by-step solution

6 steps

Part a· 3 steps

  1. Identify the connection of each electrode to the power supply.

    Electrode A is connected to the positive terminal.
    Electrode B is connected to the negative terminal.

  2. Define cathode and anode.

    The anode is the positive electrode.
    The cathode is the negative electrode.

  3. Assign the electrodes.

    Therefore, A is the anode and B is the cathode.
    Anode: A
    Cathode: B

Part b

Pb2+(l)+2e−⟶Pb(l)\text{Pb}^{2+}\text{(l)} + 2\text{e}^- \longrightarrow \text{Pb(l)}

  1. Identify the ions present in molten lead(II) bromide.

    Molten lead(II) bromide (PbBr2\text{PbBr}_2) dissociates into Pb2+\text{Pb}^{2+} ions and Br−\text{Br}^{-} ions.

  2. Write the half-equation for the cathode (reduction).

    At the cathode (negative electrode), lead(II) ions gain electrons to form lead metal.

    Pb2+(l)+2e−⟶Pb(l)\text{Pb}^{2+}\text{(l)} + 2\text{e}^- \longrightarrow \text{Pb(l)}
  3. Write the half-equation for the anode (oxidation).

    At the anode (positive electrode), bromide ions lose electrons to form bromine gas.

    2Br−(l)⟶Br2(g)+2e−2\text{Br}^{-}\text{(l)} \longrightarrow \text{Br}_2\text{(g)} + 2\text{e}^-

    Cathode equation: Pb2+(l)+2e−⟶Pb(l)\boxed{\text{Pb}^{2+}\text{(l)} + 2\text{e}^- \longrightarrow \text{Pb(l)}}
    Anode equation: 2Br−(l)⟶Br2(g)+2e−\boxed{2\text{Br}^{-}\text{(l)} \longrightarrow \text{Br}_2\text{(g)} + 2\text{e}^-}

Part c

The function of the ammeter is to measure the magnitude of the electric current flowing through the circuit.
Function: To measure the electric current.

Part d

The process of using electric current to decompose an ionic compound is called electrolysis.
Name of process: Electrolysis

Part e

An electrolyte is a substance that contains free ions and can conduct electricity when molten or dissolved in a solvent. These ions are responsible for carrying the electric charge.
Definition: An electrolyte is a substance that conducts electricity due to the movement of ions when in a molten state or dissolved in a solution.

Part f

Yes, lead(II) bromide conducts electricity in the molten state. This is because when molten, its ions (Pb2+\text{Pb}^{2+} and Br−\text{Br}^{-}) are free to move and carry charge, allowing for electrical conduction.
Conductivity: Yes

Part g

An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit, such as an electrolyte.
A suitable electrode for electrolysis, especially when inertness is required, is graphite.
Definition of electrode: An electrical conductor through which electricity enters or leaves an electrolyte.
Suitable electrode: Graphite

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