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Write equations and the expressions for Ke for these reversible reactions: (a) the reaction of hydrogen with chlorine to make hydrogen chloride.
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Step-by-step solution
4 stepsHere's how to determine if the reaction is exothermic or endothermic:
Identify the given equilibrium constant () values and their corresponding temperatures.
At , .
At (assuming in the question refers to for consistency with the first temperature unit, or if it's . The conclusion remains the same as temperature increases in both cases), .Observe the trend of as temperature changes.
As the temperature increases from to , the value of decreases from 5.1 to 1.0.
Apply Le Chatelier's principle.
For an exothermic reaction, increasing the temperature shifts the equilibrium to the left (towards reactants) to absorb the added heat. This results in a decrease in the concentration of products and an increase in the concentration of reactants, thus decreasing the value of .
For an endothermic reaction, increasing the temperature shifts the equilibrium to the right (towards products) to absorb the added heat. This results in an increase in the concentration of products and a decrease in the concentration of reactants, thus increasing the value of .Conclude whether the reaction is exothermic or endothermic.
Since an increase in temperature leads to a decrease in , the reaction is exothermic.
The reaction is exothermic.
Reason: As the temperature increases from to , the equilibrium constant decreases from 5.1 to 1.0. This indicates that increasing the temperature shifts the equilibrium to the left (towards reactants), which is characteristic of an exothermic reaction according to Le Chatelier's principle.
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