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Write the equilibrium constant expression for C(s) + CO2(g) + 2Cl2(g) <=> 2COCl2(g) and calculate Kc using the given reactions.
Chemistry
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3 stepsQuestion 1
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Equilibrium constant expression: For the reaction , the equilibrium constant expression is:
(Note: Solids like are not included in the equilibrium constant expression.)
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Calculation of the equilibrium constant: Given reactions:
- with
- with
Target reaction:
Manipulate the given reactions to obtain the target reaction.
Multiply reaction (2) by 2: $$ 2CO(g) + 2Cl_2(g) \rightleftharpoons 2COCl_2(g) $$ The new equilibrium constant for this reaction is $(K_{c2})^2$.Add reaction (1) and the modified reaction (2).
$$ C(s) + CO_2(g) \rightleftharpoons 2CO(g) $$ $$ 2CO(g) + 2Cl_2(g) \rightleftharpoons 2COCl_2(g) $$ Summing these equations and canceling $2CO(g)$ from both sides gives: $$ C(s) + CO_2(g) + 2Cl_2(g) \rightleftharpoons 2COCl_2(g) $$Calculate the overall equilibrium constant.
When reactions are added, their equilibrium constants are multiplied. $$ K_c = K_{c1} \times (K_{c2})^2 $$ $$ K_c = (1.4 \times 10^{12}) \times (5.5 \times 10^1)^2 $$ $$ K_c = (1.4 \times 10^{12}) \times (30.25 \times 10^2) $$ $$ K_c = (1.4 \times 10^{12}) \times (3.025 \times 10^3) $$ $$ K_c = (1.4 \times 3.025) \times 10^{12+3} $$ $$ K_c = 4.235 \times 10^{15} $$ The equilibrium constant for the reaction is $\mathbf{4.235 \times 10^{15}}$.
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