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Write the expression for the equilibrium constant Kp for the given reaction.

Chemistry

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Answer

0.127\text{0.127}

Step-by-step solution

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Here's the solution for question g)(ii):

g) (ii) Calculate the equilibrium constant, Kp\text{Kp} for the reaction at that temperature.

  1. Write the expression for the equilibrium constant Kp\text{Kp} for the given reaction.

    The reaction is:

    N2(g)+3H2(g)⇌2NH3(g)\text{N}_2 (\text{g}) + 3\text{H}_2 (\text{g}) \rightleftharpoons 2\text{NH}_3 (\text{g})

    The expression for Kp\text{Kp} is:

    Kp=(PNH3)2(PN2)(PH2)3\text{Kp} = \frac{(P_{\text{NH}_3})^2}{(P_{\text{N}_2})(P_{\text{H}_2})^3}
  2. Substitute the given partial pressures into the Kp\text{Kp} expression.

    Given partial pressures at equilibrium:
    PN2=1.49 atmP_{\text{N}_2} = 1.49 \text{ atm}
    PH2=0.40 atmP_{\text{H}_2} = 0.40 \text{ atm}
    PNH3=0.11 atmP_{\text{NH}_3} = 0.11 \text{ atm}

    Kp=(0.11 atm)2(1.49 atm)(0.40 atm)3\text{Kp} = \frac{(0.11 \text{ atm})^2}{(1.49 \text{ atm})(0.40 \text{ atm})^3}
  3. Calculate the value of Kp\text{Kp}.

    Kp=0.0121(1.49)(0.064)\text{Kp} = \frac{0.0121}{(1.49)(0.064)} Kp=0.01210.09536\text{Kp} = \frac{0.0121}{0.09536} Kp≈0.12688\text{Kp} \approx 0.12688

    The equilibrium constant, Kp\text{Kp}, is 0.127\boxed{\text{0.127}}.

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