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Calculate the heat of combustion of ethene at constant pressure, given the standard enthalpy of combustion is -1411 kJ/mol at 17°C.
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4 stepsHere's how to calculate the heat of combustion at constant pressure:
Write the balanced chemical equation for the combustion of ethene (alkylene, CH).
Combustion of ethene with oxygen produces carbon dioxide and water. Since water is specified to be in the liquid state, the equation is:
Calculate the change in the number of moles of gaseous substances ().
is the moles of gaseous products minus the moles of gaseous reactants.
From the balanced equation:
Gaseous products: 2 moles of
Gaseous reactants: 1 mole of moles of molesConvert the given temperature to Kelvin and the gas constant R to kJ K mol.
Given temperature .
Given gas constant .
Calculate the heat of combustion at constant pressure () using the relationship between and .
The heat of combustion at constant volume () is given as .
The formula relating and is:Substitute the values:
Rounding to two decimal places:
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