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Here are the solutions to the questions from the image. Question (c): The table below shows the observations made when aqueous ammonia was added to cations of elements E, F and G until in excess. (i)

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c(i)

G\text{G}

c(ii)

E2+(aq)+2NH3(aq)+2H2O(l)→E(OH)2(s)+2NH4+(aq)E^{2+}(aq) + 2NH_3(aq) + 2H_2O(l) \to E(OH)_2(s) + 2NH_4^+(aq)

a

N(s)\text{N(s)}

T⁺(aq)\text{T⁺(aq)}

Here are the solutions to the questions from the image.

Question (c):
The table below shows the observations made when aqueous ammonia was added to cations of elements E, F and G until in excess.

Cation ofAddition of a few drops of aqueous ammoniaAddition of excess aqueous ammonia
EWhite precipitateInsoluble
FNo precipitateNo precipitate
GWhite precipitateDissolves

(i) Select the cation that is likely to be Zn²⁺.

Zinc ions (Zn2+Zn^{2+}) react with a few drops of aqueous ammonia to form a white precipitate of zinc hydroxide, Zn(OH)2Zn(OH)_2. This precipitate then dissolves in excess aqueous ammonia to form a colorless soluble complex, tetraamminezinc(II) ion, [Zn(NH3)4]2+[Zn(NH_3)_4]^{2+}.
From the table, cation G shows a white precipitate with a few drops of aqueous ammonia, and this precipitate dissolves in excess aqueous ammonia. This behavior matches that of Zn2+Zn^{2+} ions.
The cation likely to be Zn2+Zn^{2+} is G\boxed{\text{G}}.

(ii) Given that the formula of the cation of element E is E²⁺, write the ionic equation for the reaction between E²⁺ and aqueous ammonia.

From the table, cation E forms a white precipitate with a few drops of aqueous ammonia, which is insoluble in excess aqueous ammonia. This indicates the formation of a metal hydroxide precipitate, E(OH)2E(OH)_2, which does not form a soluble ammine complex.
The reaction between E2+E^{2+} ions and aqueous ammonia (which provides hydroxide ions) forms the precipitate.

E2+(aq)+2NH3(aq)+2H2O(l)→E(OH)2(s)+2NH4+(aq)E^{2+}(aq) + 2NH_3(aq) + 2H_2O(l) \to E(OH)_2(s) + 2NH_4^+(aq)

The ionic equation is E2+(aq)+2NH3(aq)+2H2O(l)→E(OH)2(s)+2NH4+(aq)\boxed{E^{2+}(aq) + 2NH_3(aq) + 2H_2O(l) \to E(OH)_2(s) + 2NH_4^+(aq)}.

Question (a):
Study the standard electrode potential for the half-cells given below and answer the question that follow.(The letter do not represent the actual symbols of the elements)

Half-cellE° / Volts
N⁺(aq) + e⁻ → N(s)-2.92
T⁺(aq) + e⁻ → T(s)+0.52

(The specific question is cut off, but common questions for such data involve identifying oxidizing/reducing agents.)

Based on the standard electrode potentials:

  • A more negative (or less positive) E° value indicates a stronger reducing agent (the species on the right side of the half-reaction is more easily oxidized).
  • A more positive E° value indicates a stronger oxidizing agent (the species on the left side of the half-reaction is more easily reduced).

Comparing the E° values:

  • For N⁺/N: E∘=−2.92 VE^\circ = -2.92 \text{ V}
  • For T⁺/T: E∘=+0.52 VE^\circ = +0.52 \text{ V}
  • Strongest reducing agent: N(s) has the most negative reduction potential, meaning it is most easily oxidized. Therefore, N(s)\boxed{\text{N(s)}} is the strongest reducing agent.
  • Strongest oxidizing agent: T⁺(aq) has the most positive reduction potential, meaning it is most easily reduced. Therefore, T⁺(aq)\boxed{\text{T⁺(aq)}} is the strongest oxidizing agent.
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