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Here are the solutions to the questions from the image. Question (c): The table below shows the observations made when aqueous ammonia was added to cations of elements E, F and G until in excess. (i)
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Question (c):
The table below shows the observations made when aqueous ammonia was added to cations of elements E, F and G until in excess.
| Cation of | Addition of a few drops of aqueous ammonia | Addition of excess aqueous ammonia |
|---|---|---|
| E | White precipitate | Insoluble |
| F | No precipitate | No precipitate |
| G | White precipitate | Dissolves |
(i) Select the cation that is likely to be Zn²⁺.
Zinc ions () react with a few drops of aqueous ammonia to form a white precipitate of zinc hydroxide, . This precipitate then dissolves in excess aqueous ammonia to form a colorless soluble complex, tetraamminezinc(II) ion, .
From the table, cation G shows a white precipitate with a few drops of aqueous ammonia, and this precipitate dissolves in excess aqueous ammonia. This behavior matches that of ions.
The cation likely to be is .
(ii) Given that the formula of the cation of element E is E²⁺, write the ionic equation for the reaction between E²⁺ and aqueous ammonia.
From the table, cation E forms a white precipitate with a few drops of aqueous ammonia, which is insoluble in excess aqueous ammonia. This indicates the formation of a metal hydroxide precipitate, , which does not form a soluble ammine complex.
The reaction between ions and aqueous ammonia (which provides hydroxide ions) forms the precipitate.
The ionic equation is .
Question (a):
Study the standard electrode potential for the half-cells given below and answer the question that follow.(The letter do not represent the actual symbols of the elements)
| Half-cell | E° / Volts |
|---|---|
| N⁺(aq) + e⁻ → N(s) | -2.92 |
| T⁺(aq) + e⁻ → T(s) | +0.52 |
(The specific question is cut off, but common questions for such data involve identifying oxidizing/reducing agents.)
Based on the standard electrode potentials:
- A more negative (or less positive) E° value indicates a stronger reducing agent (the species on the right side of the half-reaction is more easily oxidized).
- A more positive E° value indicates a stronger oxidizing agent (the species on the left side of the half-reaction is more easily reduced).
Comparing the E° values:
- For N⁺/N:
- For T⁺/T:
- Strongest reducing agent: N(s) has the most negative reduction potential, meaning it is most easily oxidized. Therefore, is the strongest reducing agent.
- Strongest oxidizing agent: T⁺(aq) has the most positive reduction potential, meaning it is most easily reduced. Therefore, is the strongest oxidizing agent.
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