I. Nitric Acid (HNO_3)
This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.
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I. Nitric Acid ($\text{HNO}_3$)
Laboratory Preparation from Ammonia (Ostwald Process): This is an industrial process, not typically a lab preparation. It involves three main steps:
1. Catalytic oxidation of ammonia: Ammonia is oxidized with air over a platinum-rhodium catalyst at high temperature.
$$\text{4NH}_3\text{(g)} + \text{5O}_2\text{(g)} \xrightarrow{\text{Pt/Rh catalyst}} \text{4NO(g)} + \text{6H}_2\text{O(g)}$$
2. Oxidation of nitric oxide: Nitric oxide reacts with excess oxygen to form nitrogen dioxide.
$$\text{2NO(g)} + \text{O}_2\text{(g)} \to \text{2NO}_2\text{(g)}$$
3. Absorption of nitrogen dioxide: Nitrogen dioxide is absorbed in water to form nitric acid.
$$\text{3NO}_2\text{(g)} + \text{H}_2\text{O(l)} \to \text{2HNO}_3\text{(aq)} + \text{NO(g)}$$
Properties: Colorless liquid (pure), strong oxidizing agent, strong acid, corrosive. It turns yellow on standing due to decomposition into nitrogen dioxide.
Uses: Manufacture of fertilizers (e.g., ammonium nitrate), explosives (e.g., nitroglycerin, TNT), dyes, and plastics*.
Oxides of Nitrogen:
Nitrous oxide* ($\text{N}_2\text{O}$): Colorless gas, "laughing gas," neutral oxide.
Nitric oxide* ($\text{NO}$): Colorless gas, reacts with oxygen to form $\text{NO}_2$, neutral oxide.
Nitrogen dioxide* ($\text{NO}_2$): Reddish-brown gas, pungent odor, acidic oxide, contributes to acid rain.
Dinitrogen trioxide* ($\text{N}_2\text{O}_3$): Blue liquid, acidic oxide.
Dinitrogen tetroxide* ($\text{N}_2\text{O}_4$): Colorless gas/liquid, exists in equilibrium with $\text{NO}_2$.
Dinitrogen pentoxide* ($\text{N}_2\text{O}_5$): White solid, acidic oxide.
II. Carbon
Allotropes: Uses & Properties:
Diamond*:
Properties: Extremely hard, high melting point, non-conductor of electricity, transparent, high refractive index.
Uses: Cutting tools (drills, saws), abrasives, jewelry*.
Graphite*:
Properties: Soft, slippery, good conductor of electricity, high melting point, opaque.
Uses: Pencil leads, lubricants, electrodes in electrolysis, moderator* in nuclear reactors.
Amorphous Carbon* (e.g., charcoal, coke, carbon black):
Properties: Irregular structure, porous, good adsorbent.
Uses: Adsorbent (activated charcoal), fuel, pigment* (carbon black).
Laboratory Preparation of Carbon Dioxide ($\text{CO}_2$): Reaction of a carbonate (like calcium carbonate, marble chips) with a dilute acid (like hydrochloric acid).
$$\text{CaCO}_3\text{(s)} + \text{2HCl(aq)} \to \text{CaCl}_2\text{(aq)} + \text{H}_2\text{O(l)} + \text{CO}_2\text{(g)}$$
Properties and Uses of Carbon Dioxide ($\text{CO}_2$):
Properties: Colorless, odorless gas, denser than air, sparingly soluble in water (forming carbonic acid), does not support combustion, sublimes at $-78.5^\circ\text{C}$ (dry ice).
Uses: Fire extinguishers, carbonation of beverages, refrigerant (dry ice), photosynthesis* in plants.
Carbon (II) Oxide (Carbon Monoxide, $\text{CO}$):
Properties: Colorless, odorless, highly toxic gas, slightly less dense than air, burns with a blue flame, good reducing agent.
Formation: Incomplete combustion of carbon-containing fuels (e.g., in car engines, charcoal grills with insufficient oxygen).
$$\text{2C(s)} + \text{O}_2\text{(g)} \to \text{2CO(g)}$$
Coal: A fossil fuel* formed from the decomposition of plant matter over millions of years under heat and pressure. It is primarily composed of carbon with varying amounts of other elements.
Uses: Major source of energy for electricity generation, production of coke, and as a chemical feedstock*.
Coke: A solid carbonaceous residue derived from destructive distillation of coal* in the absence of air. It is a purer form of carbon than coal.
Uses: Reducing agent in blast furnaces for iron extraction, fuel (e.g., in foundries), production of synthesis gas*.

