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Identify the gaseous species in the reaction.

Chemistry

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  1. Identify the gaseous species in the reaction.

    The given reaction is:

    A(s)+2B(g)⇌2C(aq)+D(g)\text{A}_{(s)} + 2\text{B}_{(g)} \rightleftharpoons 2\text{C}_{(aq)} + \text{D}_{(g)}

    When considering the effect of pressure on equilibrium, we only look at the gaseous reactants and products. Solids (A(s)\text{A}_{(s)}) and aqueous solutions (C(aq)\text{C}_{(aq)}) are not significantly affected by changes in pressure.

  2. Count the total moles of gas on each side of the reaction.

    • Reactant side: We have 2B(g)2\text{B}_{(g)}, which means there are 2 moles of gas.
    • Product side: We have D(g)\text{D}_{(g)}, which means there is 1 mole of gas.
  3. Apply Le Chatelier's Principle.

    Le Chatelier's Principle states that if a change of condition is applied to a system in equilibrium, the system will shift in a direction that relieves the stress.

    • A decrease in pressure favors the side of the reaction with a greater number of moles of gas.
    • An increase in pressure favors the side of the reaction with a fewer number of moles of gas.
  4. Determine the direction of the shift.

    On the reactant side, there are 2 moles of gas.
    On the product side, there is 1 mole of gas.
    Since the reactant side has more moles of gas (2 moles > 1 mole), a decrease in pressure will cause the equilibrium to shift towards the reactant side. This means the backward reaction will be favored.

  5. Evaluate the given options.

    • A. rate of forward reaction will increase: Incorrect. The equilibrium shifts to the left, favoring the backward reaction.
    • B. rates of forward and backward reaction are not affected: Incorrect. Pressure changes affect equilibria involving gases.
    • C. rate of backward reaction will increase: Correct. When the equilibrium shifts to the left, the rate of the backward reaction increases relative to the forward reaction to re-establish equilibrium.
    • D. the equilibrium will shift: While true, option C provides a more specific and accurate description of how the equilibrium shifts in terms of reaction rates.

    The final answer is C\boxed{\text{C}}

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