In a reaction 20cm3 of 0.1M sodium carbonate completely reacted with 13cm3 of dilute sulphuric acid.find the molarity of the sulphuric acid used

Chemistry

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Step 1: Write the balanced chemical equation.
The reaction between sodium carbonate (Na2CO3\text{Na}_2\text{CO}_3) and sulphuric acid (H2SO4\text{H}_2\text{SO}_4) is:

Na2CO3(aq)+H2SO4(aq)→Na2SO4(aq)+H2O(l)+CO2(g)\text{Na}_2\text{CO}_3 (aq) + \text{H}_2\text{SO}_4 (aq) \rightarrow \text{Na}_2\text{SO}_4 (aq) + \text{H}_2\text{O} (l) + \text{CO}_2 (g)

From the balanced equation, the mole ratio of Na2CO3\text{Na}_2\text{CO}_3 to H2SO4\text{H}_2\text{SO}_4 is 1:11:1.

Step 2: Calculate the moles of sodium carbonate.
Given:
Volume of Na2CO3=20 cm3=0.020 dm3\text{Na}_2\text{CO}_3 = 20 \text{ cm}^3 = 0.020 \text{ dm}^3
Molarity of Na2CO3=0.1 M\text{Na}_2\text{CO}_3 = 0.1 \text{ M}
Moles of Na2CO3=Molarity×Volume\text{Na}_2\text{CO}_3 = \text{Molarity} \times \text{Volume}

Moles of Na2CO3=0.1 mol/dm3×0.020 dm3=0.002 mol\text{Moles of } \text{Na}_2\text{CO}_3 = 0.1 \text{ mol/dm}^3 \times 0.020 \text{ dm}^3 = 0.002 \text{ mol}

Step 3: Determine the moles of sulphuric acid.
Since the mole ratio of Na2CO3\text{Na}_2\text{CO}_3 to H2SO4\text{H}_2\text{SO}_4 is 1:11:1, the moles of H2SO4\text{H}_2\text{SO}_4 reacted are equal to the moles of Na2CO3\text{Na}_2\text{CO}_3.

Moles of H2SO4=0.002 mol\text{Moles of } \text{H}_2\text{SO}_4 = 0.002 \text{ mol}

Step 4: Calculate the molarity of sulphuric acid.
Given:
Volume of H2SO4=13 cm3=0.013 dm3\text{H}_2\text{SO}_4 = 13 \text{ cm}^3 = 0.013 \text{ dm}^3
Molarity of $\text{H}_2\text{SO}_4 = \frac{\text{Moles of } \text{H}_2\text{SO}_4}{\text{Volume of } \text{H}_2\text{SO}_4 \text{ (in dm}^3)} $$

Molarity of H2SO4=0.002 mol0.013 dm3≈0.1538 M\text{Molarity of } \text{H}_2\text{SO}_4 = \frac{0.002 \text{ mol}}{0.013 \text{ dm}^3} \approx 0.1538 \text{ M}

Rounding to three significant figures:

Molarity of H2SO4≈0.154 M\text{Molarity of } \text{H}_2\text{SO}_4 \approx 0.154 \text{ M}

The molarity of the sulphuric acid used is 0.154 M\boxed{\text{0.154 M}}.

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