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Determine the order of the reaction given the rate constant K = 5.5 x 10⁻¹⁴ s⁻¹.

Chemistry

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Answer

प्रथम कोटि की अभिक्रिया\text{प्रथम कोटि की अभिक्रिया}

Step-by-step solution

4 steps
  1. Identify the given rate constant and its units.

    The given rate constant is K=5.5×10−14 s−1K = 5.5 \times 10^{-14} \text{ s}^{-1}. The unit of the rate constant is s−1\text{s}^{-1}.

  2. Recall the general units for the rate constant.

    For an nn-th order reaction, the general units of the rate constant KK are given by:

    Units of K=(concentration)1−n(time)−1\text{Units of } K = (\text{concentration})^{1-n} (\text{time})^{-1}

    If concentration is in mol L−1\text{mol L}^{-1} and time is in seconds (s\text{s}), then:

    Units of K=(mol L−1)1−n s−1\text{Units of } K = (\text{mol L}^{-1})^{1-n} \text{ s}^{-1}
  3. Compare the given units with the general formula to find the order nn.

    We are given that the units of KK are s−1\text{s}^{-1}.
    Comparing this with (mol L−1)1−n s−1(\text{mol L}^{-1})^{1-n} \text{ s}^{-1}, we can see that the concentration term (mol L−1)1−n(\text{mol L}^{-1})^{1-n} must be equal to 1. This happens when the exponent (1−n)(1-n) is 0.

    1−n=01-n = 0 n=1n = 1
  4. State the order of the reaction.

    Since n=1n=1, the reaction is a first-order reaction.

    The order of the reaction is first order.

    प्रथम कोटि की अभिक्रिया\text{प्रथम कोटि की अभिक्रिया}
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