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Question 28(b): Explain why copper displaces Q from its nitrate solution, given the standard electrode potentials.

Chemistry

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Here is the answer for question 28 b):

b)

  1. Compare the standard electrode potentials (E∘E^\circ) of copper and Q.

    ECu2+/Cu∘=+0.34 VE^\circ_{Cu^{2+}/Cu} = +0.34 \text{ V}
    EQ+/Q∘=+0.80 VE^\circ_{Q^+/Q} = +0.80 \text{ V}

  2. Determine the relative reactivity.

    Since ECu2+/Cu∘E^\circ_{Cu^{2+}/Cu} is less positive than EQ+/Q∘E^\circ_{Q^+/Q}, copper metal is a stronger reducing agent (more easily oxidized) than metal Q.

  3. Explain the reaction.

    Because copper is a stronger reducing agent, it will spontaneously reduce the Q+Q^+ ions in the solution to solid Q, while the copper metal itself gets oxidized to Cu2+Cu^{2+} ions. This means copper displaces Q from its nitrate solution.

    Reason: Copper is a stronger reducing agent (more reactive) than metal Q. Therefore, copper metal is oxidized to Cu2+Cu^{2+} ions, causing the copper strip to dissolve, while Q+Q^+ ions are reduced to solid Q, which deposits on the copper strip.

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