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Separate the reaction into half-reactions.

Chemistry

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To balance the redox reaction MnO4−(aq)+Fe2+(aq)→Mn2+(aq)+Fe3+(aq)\text{MnO}_4^- (aq) + \text{Fe}^{2+} (aq) \rightarrow \text{Mn}^{2+} (aq) + \text{Fe}^{3+} (aq) in an acidic medium using the half-reaction method:

  1. Separate the reaction into half-reactions.

    Oxidation half-reaction: Fe2+(aq)→Fe3+(aq)\text{Fe}^{2+} (aq) \rightarrow \text{Fe}^{3+} (aq)
    Reduction half-reaction: MnO4−(aq)→Mn2+(aq)\text{MnO}_4^- (aq) \rightarrow \text{Mn}^{2+} (aq)

  2. Balance atoms other than oxygen and hydrogen.

    The Fe atoms are balanced. The Mn atoms are balanced.

  3. Balance oxygen atoms by adding H2O\text{H}_2\text{O}.

    Oxidation: Fe2+(aq)→Fe3+(aq)\text{Fe}^{2+} (aq) \rightarrow \text{Fe}^{3+} (aq)
    Reduction: MnO4−(aq)→Mn2+(aq)+4H2O(l)\text{MnO}_4^- (aq) \rightarrow \text{Mn}^{2+} (aq) + 4\text{H}_2\text{O} (l)

  4. Balance hydrogen atoms by adding H+\text{H}^+.

    Oxidation: Fe2+(aq)→Fe3+(aq)\text{Fe}^{2+} (aq) \rightarrow \text{Fe}^{3+} (aq)
    Reduction: MnO4−(aq)+8H+(aq)→Mn2+(aq)+4H2O(l)\text{MnO}_4^- (aq) + 8\text{H}^+ (aq) \rightarrow \text{Mn}^{2+} (aq) + 4\text{H}_2\text{O} (l)

  5. Balance the charge by adding electrons (e−\text{e}^-).

    Oxidation:
    Reactant charge: +2+2
    Product charge: +3+3
    Add 1 electron to the product side:

    Fe2+(aq)→Fe3+(aq)+e−\text{Fe}^{2+} (aq) \rightarrow \text{Fe}^{3+} (aq) + \text{e}^-

    Reduction:
    Reactant charge: (−1)+8(+1)=+7(-1) + 8(+1) = +7
    Product charge: +2+2
    Add 5 electrons to the reactant side:

    MnO4−(aq)+8H+(aq)+5e−→Mn2+(aq)+4H2O(l)\text{MnO}_4^- (aq) + 8\text{H}^+ (aq) + 5\text{e}^- \rightarrow \text{Mn}^{2+} (aq) + 4\text{H}_2\text{O} (l)
  6. Multiply the half-reactions to equalize the number of electrons.

    Multiply the oxidation half-reaction by 5:

    5Fe2+(aq)→5Fe3+(aq)+5e−5\text{Fe}^{2+} (aq) \rightarrow 5\text{Fe}^{3+} (aq) + 5\text{e}^-

    The reduction half-reaction remains the same:

    MnO4−(aq)+8H+(aq)+5e−→Mn2+(aq)+4H2O(l)\text{MnO}_4^- (aq) + 8\text{H}^+ (aq) + 5\text{e}^- \rightarrow \text{Mn}^{2+} (aq) + 4\text{H}_2\text{O} (l)
  7. Add the balanced half-reactions and cancel common species.

    5Fe2+(aq)+MnO4−(aq)+8H+(aq)+5e−→5Fe3+(aq)+5e−+Mn2+(aq)+4H2O(l)5\text{Fe}^{2+} (aq) + \text{MnO}_4^- (aq) + 8\text{H}^+ (aq) + 5\text{e}^- \rightarrow 5\text{Fe}^{3+} (aq) + 5\text{e}^- + \text{Mn}^{2+} (aq) + 4\text{H}_2\text{O} (l)

    Cancel the 5 electrons from both sides:

    5Fe2+(aq)+MnO4−(aq)+8H+(aq)→5Fe3+(aq)+Mn2+(aq)+4H2O(l)5\text{Fe}^{2+} (aq) + \text{MnO}_4^- (aq) + 8\text{H}^+ (aq) \rightarrow 5\text{Fe}^{3+} (aq) + \text{Mn}^{2+} (aq) + 4\text{H}_2\text{O} (l)
  8. Verify that atoms and charges are balanced.

    Atoms: Fe (5), Mn (1), O (4), H (8) are balanced on both sides.
    Charge: Reactants: 5(+2)+(−1)+8(+1)=+10−1+8=+175(+2) + (-1) + 8(+1) = +10 - 1 + 8 = +17. Products: 5(+3)+(+2)+0=+15+2=+175(+3) + (+2) + 0 = +15 + 2 = +17. Charges are balanced.

    The balanced redox reaction is:

    5Fe2+(aq)+MnO4−(aq)+8H+(aq)→5Fe3+(aq)+Mn2+(aq)+4H2O(l)\boxed{5\text{Fe}^{2+} (aq) + \text{MnO}_4^- (aq) + 8\text{H}^+ (aq) \rightarrow 5\text{Fe}^{3+} (aq) + \text{Mn}^{2+} (aq) + 4\text{H}_2\text{O} (l)}

    Identifying the oxidizing and reducing agents:

    • The species that is oxidized (loses electrons) is the reducing agent. Here, Fe2+\text{Fe}^{2+} is oxidized to Fe3+\text{Fe}^{3+}.
    • The species that is reduced (gains electrons) is the oxidizing agent. Here, MnO4−\text{MnO}_4^- is reduced to Mn2+\text{Mn}^{2+}.

    Oxidizing agent: MnO4−\boxed{\text{MnO}_4^-}
    Reducing agent: Fe2+\boxed{\text{Fe}^{2+}}

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