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Separate the reaction into half-reactions.
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8 stepsTo balance the redox reaction in an acidic medium using the half-reaction method:
Separate the reaction into half-reactions.
Oxidation half-reaction:
Reduction half-reaction:Balance atoms other than oxygen and hydrogen.
The Fe atoms are balanced. The Mn atoms are balanced.
Balance oxygen atoms by adding .
Oxidation:
Reduction:Balance hydrogen atoms by adding .
Oxidation:
Reduction:Balance the charge by adding electrons ().
Oxidation:
Reactant charge:
Product charge:
Add 1 electron to the product side:Reduction:
Reactant charge:
Product charge:
Add 5 electrons to the reactant side:Multiply the half-reactions to equalize the number of electrons.
Multiply the oxidation half-reaction by 5:
The reduction half-reaction remains the same:
Add the balanced half-reactions and cancel common species.
Cancel the 5 electrons from both sides:
Verify that atoms and charges are balanced.
Atoms: Fe (5), Mn (1), O (4), H (8) are balanced on both sides.
Charge: Reactants: . Products: . Charges are balanced.The balanced redox reaction is:
Identifying the oxidizing and reducing agents:
- The species that is oxidized (loses electrons) is the reducing agent. Here, is oxidized to .
- The species that is reduced (gains electrons) is the oxidizing agent. Here, is reduced to .
Oxidizing agent:
Reducing agent:
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