This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.

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Here's the solution to question (a)(iv):
a) (iv) Explain why silicon dioxide exists as a solid of high melting point whereas carbon dioxide is a gas even though silicon and carbon belong to the same group.
Step 1: Describe the structure of carbon dioxide. Carbon dioxide () is a simple molecular substance. It consists of discrete molecules held together by weak intermolecular forces (van der Waals forces).
Step 2: Describe the structure of silicon dioxide. Silicon dioxide () has a giant covalent network structure. Each silicon atom is covalently bonded to four oxygen atoms, and each oxygen atom is covalently bonded to two silicon atoms, forming a continuous three-dimensional network.
Step 3: Relate the structures to their physical properties. To melt , only a small amount of energy is required to overcome the weak intermolecular forces, which is why it is a gas at room temperature. In contrast, to melt , a large amount of energy is needed to break the strong covalent bonds throughout its giant network structure, resulting in a high melting point and solid state at room temperature.
The difference in structure is due to carbon's ability to form stable double bonds with oxygen, leading to discrete molecules, while silicon prefers to form single bonds with oxygen, leading to an extended network.
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Here's the solution to question (a)(iv): a) (iv) Explain why silicon dioxide exists as a solid of high melting point whereas carbon dioxide is a gas even though silicon and carbon belong to the same group.
This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.