Structure 𝖔𝖋 π–‰π–”π–šπ–‡π–‘π–† 𝖇𝖔𝖓𝖉?

Chemistry

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A double bond is a covalent bond formed between two atoms where they share four electrons (two pairs of electrons).

It consists of two main components:

  • One sigma (Οƒ\sigma) bond: This is formed by the direct, head-on overlap of atomic orbitals (e.g., sp2\text{sp}^2 hybrid orbitals in carbon-carbon double bonds). It is a strong bond.
  • One pi (Ο€\pi) bond: This is formed by the sideways overlap of unhybridized p-orbitals above and below the plane of the sigma bond. The pi bond is generally weaker than the sigma bond.

The presence of a double bond results in a shorter bond length and higher bond energy compared to a single bond between the same two atoms. The pi bond also restricts rotation around the bond axis, leading to geometric isomerism (cis/trans isomers).

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