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Chemistry

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6. (b) Study the flow chart below and use it to answer the questions that follow.

  • (i) Identify the organic compound K. Sodium propanoate (CH3CH2COONa\text{CH}_3\text{CH}_2\text{COONa}) undergoes decarboxylation with sodalime (NaOH/CaO\text{NaOH}/\text{CaO}). This removes the carboxylate group, forming an alkane with one less carbon atom.

    • Organic compound K: Ethane (CH3CH3\text{CH}_3\text{CH}_3)
  • (ii) Write the formula of M. Prop-1-ene (CH3CH=CH2\text{CH}_3\text{CH}=\text{CH}_2) reacts with chlorine gas (Cl2(g)\text{Cl}_2(g)) in an addition reaction across the double bond.

    • Formula of M: CH3CHClCH2Cl\text{CH}_3\text{CHClCH}_2\text{Cl} (1,2-Dichloropropane)
  • (iii) Give one reagent that can be used in

    • (a) Step I: Propanoic acid (CH3CH2COOH\text{CH}_3\text{CH}_2\text{COOH}) is reduced to Propan-1-ol (CH3CH2CH2OH\text{CH}_3\text{CH}_2\text{CH}_2\text{OH}).
      • Reagent: Lithium aluminium hydride (LiAlH4\text{LiAlH}_4)
    • (b) Step II: Propan-1-ol (CH3CH2CH2OH\text{CH}_3\text{CH}_2\text{CH}_2\text{OH}) is oxidized to Propanoic acid (CH3CH2COOH\text{CH}_3\text{CH}_2\text{COOH}).
      • Reagent: Acidified potassium dichromate(VI) (K2Cr2O7/H+\text{K}_2\text{Cr}_2\text{O}_7/\text{H}^+) or acidified potassium permanganate(VII) (KMnO4/H+\text{KMnO}_4/\text{H}^+)
  • (iv) Write the equation of the reaction in step III. Propan-1-ol (CH3CH2CH2OH\text{CH}_3\text{CH}_2\text{CH}_2\text{OH}) reacts with sodium metal (Na\text{Na}).

    2CH3CH2CH2OH(l)+2Na(s)→2CH3CH2CH2ONa(aq)+H2(g)2\text{CH}_3\text{CH}_2\text{CH}_2\text{OH}(l) + 2\text{Na}(s) \rightarrow 2\text{CH}_3\text{CH}_2\text{CH}_2\text{ONa}(aq) + \text{H}_2(g)

6. (c) The structure below represents a type of a cleaning agent.
The structure is not visible in the provided image.

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