This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.

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Here are the solutions to question 19(a) based on the provided image.
Question 19(a): Study the standard electrode potential for the half-cells given below and answer the question that follow.(The letter do not represent the actual symbols of the elements)
| Half-cell | E° / Volts | | :-------- | :--------- | | N⁺(aq) + e⁻ → N(s) | -2.92 | | J⁺(aq) + e⁻ → J(s) | +0.52 | | K⁺(aq) + e⁻ → K(s) | 0.00 | | ½ G₂(g) + e⁻ → G⁻(aq) | +1.36 | | M²⁺(aq) + 2e⁻ → M(s) | -0.44 |
(i) Identify the strongest oxidizing agents. Give a reason for your answer.
Step 1: Identify the half-cell with the most positive standard electrode potential (E°). The standard electrode potentials are: • N⁺/N: • J⁺/J: • K⁺/K: • ½ G₂/G⁻: • M²⁺/M: The most positive E° value is for the ½ G₂(g) + e⁻ → G⁻(aq) half-reaction.
Step 2: Determine the strongest oxidizing agent. A strong oxidizing agent is a species that is easily reduced (has a high tendency to gain electrons). This corresponds to the half-reaction with the most positive standard electrode potential. The species being reduced in this half-reaction is G₂.
The strongest oxidizing agent is . Reason:
(ii) Which two half-cells would produce the highest potential difference when combined?
Step 1: Identify the half-cell with the most positive E° (for reduction at the cathode). This is ½ G₂(g) + e⁻ → G⁻(aq) with .
Step 2: Identify the half-cell with the most negative E° (for oxidation at the anode). This is N⁺(aq) + e⁻ → N(s) with .
Step 3: Calculate the potential difference (E° cell). The two half-cells that would produce the highest potential difference are .
(iii) In the space below draw a complete electrochemical cell of the two-half cells mentioned in (ii) above.
An electrochemical cell using N⁺/N and ½ G₂/G⁻ half-cells would have: • Anode (Oxidation): N(s) electrode immersed in N⁺(aq) solution. (N is oxidized: ) • Cathode (Reduction): An inert electrode (e.g., Platinum, Pt) immersed in G⁻(aq) solution, with G₂(g) bubbled over it. (G₂ is reduced: ) • Electron flow: From N electrode (anode) to Pt electrode (cathode). • Salt bridge: Connects the two solutions to maintain charge neutrality. • Voltmeter: Connected externally between the two electrodes.
\begin{tikzpicture}[scale=0.8] % Beaker 1 (Anode) \draw (0,0) -- (0,3) -- (3,3) -- (3,0) -- cycle; \draw[fill=gray!30] (0.5,0.5) rectangle (2.5,2.5); % Solution \node at (1.5,1.5) {N⁺(aq)}; \draw[thick] (1.5,0.5) -- (1.5,2.5); % Electrode \draw[thick, fill=gray] (1.5,2.5) circle (0.1); % Electrode top \node at (1.5,2.8) {N(s)}; \node at (1.5,-0.5) {Anode}; % Beaker 2 (Cathode) \draw (7,0) -- (7,3) -- (10,3) -- (10,0) -- cycle; \draw[fill=gray!30] (7.5,0.5) rectangle (9.5,2.5); % Solution \node at (8.5,1.5) {G⁻(aq)}; \draw[thick] (8.5,0.5) -- (8.5,2.5); % Electrode \draw[thick, fill=gray] (8.5,2.5) circle (0.1); % Electrode top \node at (8.5,2.8) {Pt(s)}; \node at (8.5,-0.5) {Cathode}; \draw[->] (9.2,1.8) -- (8.8,1.8); % Gas inlet \node at (9.5,1.8) {G₂(g)}; % Voltmeter \draw (1.5,3) -- (1.5,4) -- (5,4) node[above] {Voltmeter} -- (8.5,4) -- (8.5,3); \draw (5,4) circle (0.5); \node at (5,4) {V}; % Electron flow \draw[->, very thick, blue] (1.5,3.5) -- (4.5,3.5); \draw[->, very thick, blue] (5.5,3.5) -- (8.5,3.5); \node[above, blue] at (5,3.5) {e⁻ flow}; % Salt bridge \draw[thick] (2.5,3) arc (0:180:3.5cm and 0.5cm); \draw[thick] (2.5,3) -- (2.5,2.5); \draw[thick] (7.5,3) -- (7.5,2.5); \node at (5,3.5) [below] {Salt Bridge}; \end{tikzpicture}That's 2 down. 3 left today — send the next one.
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This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.