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What is the correct IUPAC name for the compound CH2=CH−CH2−CH2OH?

Chemistry

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Answer

But-3-en-1-ol\text{But-3-en-1-ol}

The statement in the image is incorrect regarding the name "4-Buten-1-ol".

Here's the correction and explanation:

1. Identify the functional groups and determine priority:
The compound is CH2=CH−CH2−CH2OH\text{CH}_2=\text{CH}-\text{CH}_2-\text{CH}_2\text{OH}.
It contains two functional groups:

  • A hydroxyl group (-OH\text{-OH}), which makes it an alcohol.
  • A carbon-carbon double bond (C=C\text{C}=\text{C}), which makes it an alkene. According to IUPAC rules, the hydroxyl group (-OH\text{-OH}) has higher priority than the double bond.

2. Number the carbon chain:
The carbon chain must be numbered such that the highest priority functional group (the hydroxyl group) receives the lowest possible number.

CH24=CH3−CH22−CH21OH\overset{4}{\text{CH}_2}=\overset{3}{\text{CH}}-\overset{2}{\text{CH}_2}-\overset{1}{\text{CH}_2}\text{OH}
  • The hydroxyl group is on carbon 1.
  • The double bond starts at carbon 3 (between carbon 3 and carbon 4).

3. Construct the IUPAC name:

  • The parent chain has 4 carbons, so the base name is "but-".
  • The double bond is at position 3, so it's "but-3-en-".
  • The alcohol group is at position 1, so it's "-1-ol".

Combining these, the correct IUPAC name is But-3-en-1-ol.

Conclusion:
The image correctly identifies that "1-Buten-4-ol" is incorrect because the alcohol group must have the lowest possible number. However, the name "4-Buten-1-ol" is also incorrect because the double bond is at position 3, not 4. The position of a double bond is indicated by the lower-numbered carbon atom involved in the bond.

The correct IUPAC name for CH2=CH−CH2−CH2OH\text{CH}_2=\text{CH}-\text{CH}_2-\text{CH}_2\text{OH} is But-3-en-1-ol\boxed{\text{But-3-en-1-ol}}.

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