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The ionization energies for an element are given as: IE1 = 1290 kJ/mol, IE2 = 3370 kJ/mol, IE3 = 5320 kJ/mol, IE4 = 7440 kJ/mol, IE5 = 10900 kJ/mol, IE6 = 3010 kJ/mol, IE7 = 70900 kJ/mol. Identify the
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Analyze the given ionization energies.
The ionization energies are:
IE1 = 1290 kJ/mol
IE2 = 3370 kJ/mol
IE3 = 5320 kJ/mol
IE4 = 7440 kJ/mol
IE5 = 10900 kJ/mol
IE6 = 3010 kJ/mol
IE7 = 70900 kJ/molSuccessive ionization energies should always increase because it takes more energy to remove an electron from an increasingly positive ion. The value for IE6 (3010 kJ/mol) is lower than IE5 (10900 kJ/mol), which indicates a likely typo in the question. However, we can still identify the significant jump that indicates the removal of a core electron.
Identify the largest jump in ionization energy.
A very large increase in ionization energy occurs when an electron is removed from a stable, filled inner electron shell (core electron) compared to removing a valence electron.
Let's look at the ratios of successive ionization energies, focusing on the largest increase:
Ratio IE2/IE1 =
Ratio IE3/IE2 =
Ratio IE4/IE3 =
Ratio IE5/IE4 =
Ratio IE7/IE6 = (This is the largest relative jump, despite the problematic IE6 value).Determine the number of valence electrons.
The extremely large jump between IE6 and IE7 indicates that the first 6 electrons are valence electrons, and the 7th electron is a core electron. Therefore, the atom has 6 valence electrons.
Determine the electronic configuration.
The element is between Li (atomic number 3) and Ne (atomic number 10). An element in the second period with 6 valence electrons is Oxygen (O), which has an atomic number of 8.
The electronic configuration for Oxygen is .
The question asks for the electronic configuration of the atom, typically referring to the valence shell configuration for elements in the second period.The valence electronic configuration is .
Match with the given options.
The configuration matches option D.
The final answer is .
Part 26
Determine the number of half-lives.
The fraction of the radioisotope remaining is of its original value.
The formula for radioactive decay is:where is the amount remaining, is the initial amount, and is the number of half-lives.
Substitute the given fraction:We know that , so .
Therefore, the number of half-lives, , is 4.Calculate the half-life.
The total time elapsed is given as 96.8 days.
The total time is also equal to the number of half-lives multiplied by the half-life period ():Substitute the known values:
Solve for :
Match with the given options.
The calculated half-life of 24.2 days matches option B.
The final answer is .
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