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The ionization energies for an element are given as: IE1 = 1290 kJ/mol, IE2 = 3370 kJ/mol, IE3 = 5320 kJ/mol, IE4 = 7440 kJ/mol, IE5 = 10900 kJ/mol, IE6 = 3010 kJ/mol, IE7 = 70900 kJ/mol. Identify the

Chemistry

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2 parts
25

D. 2s22p4\text{D. } 2s^22p^4

26

B. 24.2 days\text{B. } 24.2 \text{ days}

Step-by-step solution

8 steps

Part 25· 5 steps

  1. Analyze the given ionization energies.

    The ionization energies are:
    IE1 = 1290 kJ/mol
    IE2 = 3370 kJ/mol
    IE3 = 5320 kJ/mol
    IE4 = 7440 kJ/mol
    IE5 = 10900 kJ/mol
    IE6 = 3010 kJ/mol
    IE7 = 70900 kJ/mol

    Successive ionization energies should always increase because it takes more energy to remove an electron from an increasingly positive ion. The value for IE6 (3010 kJ/mol) is lower than IE5 (10900 kJ/mol), which indicates a likely typo in the question. However, we can still identify the significant jump that indicates the removal of a core electron.

  2. Identify the largest jump in ionization energy.

    A very large increase in ionization energy occurs when an electron is removed from a stable, filled inner electron shell (core electron) compared to removing a valence electron.
    Let's look at the ratios of successive ionization energies, focusing on the largest increase:
    Ratio IE2/IE1 = 3370/1290≈2.613370/1290 \approx 2.61
    Ratio IE3/IE2 = 5320/3370≈1.585320/3370 \approx 1.58
    Ratio IE4/IE3 = 7440/5320≈1.407440/5320 \approx 1.40
    Ratio IE5/IE4 = 10900/7440≈1.4610900/7440 \approx 1.46
    Ratio IE7/IE6 = 70900/3010≈23.5570900/3010 \approx 23.55 (This is the largest relative jump, despite the problematic IE6 value).

  3. Determine the number of valence electrons.

    The extremely large jump between IE6 and IE7 indicates that the first 6 electrons are valence electrons, and the 7th electron is a core electron. Therefore, the atom has 6 valence electrons.

  4. Determine the electronic configuration.

    The element is between Li (atomic number 3) and Ne (atomic number 10). An element in the second period with 6 valence electrons is Oxygen (O), which has an atomic number of 8.
    The electronic configuration for Oxygen is 1s22s22p41s^2 2s^2 2p^4.
    The question asks for the electronic configuration of the atom, typically referring to the valence shell configuration for elements in the second period.

    The valence electronic configuration is 2s22p42s^2 2p^4.

  5. Match with the given options.

    The configuration 2s22p42s^2 2p^4 matches option D.

    The final answer is D. 2s22p4\boxed{\text{D. } 2s^22p^4}.

Part 26

B. 24.2 days\text{B. } 24.2 \text{ days}

  1. Determine the number of half-lives.

    The fraction of the radioisotope remaining is 116\frac{1}{16} of its original value.
    The formula for radioactive decay is:

    NN0=(12)n\frac{N}{N_0} = \left(\frac{1}{2}\right)^n

    where NN is the amount remaining, N0N_0 is the initial amount, and nn is the number of half-lives.
    Substitute the given fraction:

    116=(12)n\frac{1}{16} = \left(\frac{1}{2}\right)^n

    We know that 24=162^4 = 16, so (12)4=116\left(\frac{1}{2}\right)^4 = \frac{1}{16}.
    Therefore, the number of half-lives, nn, is 4.

  2. Calculate the half-life.

    The total time elapsed is given as 96.8 days.
    The total time is also equal to the number of half-lives multiplied by the half-life period (t1/2t_{1/2}):

    t=n×t1/2t = n \times t_{1/2}

    Substitute the known values:

    96.8 days=4×t1/296.8 \text{ days} = 4 \times t_{1/2}

    Solve for t1/2t_{1/2}:

    t1/2=96.8 days4t_{1/2} = \frac{96.8 \text{ days}}{4} t1/2=24.2 dayst_{1/2} = 24.2 \text{ days}
  3. Match with the given options.

    The calculated half-life of 24.2 days matches option B.

    The final answer is B. 24.2 days\boxed{\text{B. } 24.2 \text{ days}}.

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