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4 stepsHere's the derivation for the free energy change for the given reaction.
The reaction is:
Define the change in Gibbs free energy for the reaction.
For a chemical reaction, the change in Gibbs free energy () is the sum of the chemical potentials of the products minus the sum of the chemical potentials of the reactants, each multiplied by its stoichiometric coefficient.
where is the chemical potential of component .
Express the chemical potential for an ideal gas.
For an ideal gas, the chemical potential () of component at a given partial pressure and temperature is related to its standard chemical potential () by:
Here, is the ideal gas constant, is the absolute temperature, and is the standard pressure (usually or ).
Substitute the chemical potential expressions into the equation.
Substitute the expression for for each component into the equation:
Rearrange and simplify the expression.
Group the standard chemical potential terms and the logarithmic terms:
The term represents the standard Gibbs free energy change for the reaction, .
Combine the logarithmic terms using the properties of logarithms ( and ):
The term inside the logarithm is the reaction quotient () for partial pressures, where the partial pressures are divided by the standard pressure :
Since the sum of the stoichiometric coefficients for products () equals the sum for reactants (), the terms cancel out in this specific case, simplifying to:
Therefore, the expression for the free energy change for the reaction is:
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