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Answer

ΔG=ΔG∘+RTln⁡Qp\Delta G = \Delta G^{\circ} + RT \ln Q_p

Step-by-step solution

4 steps

Here's the derivation for the free energy change for the given reaction.

The reaction is:

A(g)+B(g)→C(g)+D(g)\text{A}_{(\text{g})} + \text{B}_{(\text{g})} \rightarrow \text{C}_{(\text{g})} + \text{D}_{(\text{g})}
  1. Define the change in Gibbs free energy for the reaction.

    For a chemical reaction, the change in Gibbs free energy (ΔG\Delta G) is the sum of the chemical potentials of the products minus the sum of the chemical potentials of the reactants, each multiplied by its stoichiometric coefficient.

    ΔG=(μC+μD)−(μA+μB)\Delta G = (\mu_C + \mu_D) - (\mu_A + \mu_B)

    where μi\mu_i is the chemical potential of component ii.

  2. Express the chemical potential for an ideal gas.

    For an ideal gas, the chemical potential (μi\mu_i) of component ii at a given partial pressure PiP_i and temperature TT is related to its standard chemical potential (μi∘\mu_i^{\circ}) by:

    μi=μi∘+RTln⁡(PiP∘)\mu_i = \mu_i^{\circ} + RT \ln\left(\frac{P_i}{P^{\circ}}\right)

    Here, RR is the ideal gas constant, TT is the absolute temperature, and P∘P^{\circ} is the standard pressure (usually 1 bar1 \, \text{bar} or 1 atm1 \, \text{atm}).

  3. Substitute the chemical potential expressions into the ΔG\Delta G equation.

    Substitute the expression for μi\mu_i for each component into the ΔG\Delta G equation:

    ΔG=[μC∘+RTln⁡(PCP∘)]+[μD∘+RTln⁡(PDP∘)]−[μA∘+RTln⁡(PAP∘)]−[μB∘+RTln⁡(PBP∘)]\Delta G = \left[\mu_C^{\circ} + RT \ln\left(\frac{P_C}{P^{\circ}}\right)\right] + \left[\mu_D^{\circ} + RT \ln\left(\frac{P_D}{P^{\circ}}\right)\right] - \left[\mu_A^{\circ} + RT \ln\left(\frac{P_A}{P^{\circ}}\right)\right] - \left[\mu_B^{\circ} + RT \ln\left(\frac{P_B}{P^{\circ}}\right)\right]
  4. Rearrange and simplify the expression.

    Group the standard chemical potential terms and the logarithmic terms:

    ΔG=(μC∘+μD∘−μA∘−μB∘)+RT[ln⁡(PCP∘)+ln⁡(PDP∘)−ln⁡(PAP∘)−ln⁡(PBP∘)]\Delta G = (\mu_C^{\circ} + \mu_D^{\circ} - \mu_A^{\circ} - \mu_B^{\circ}) + RT \left[\ln\left(\frac{P_C}{P^{\circ}}\right) + \ln\left(\frac{P_D}{P^{\circ}}\right) - \ln\left(\frac{P_A}{P^{\circ}}\right) - \ln\left(\frac{P_B}{P^{\circ}}\right)\right]

    The term (μC∘+μD∘−μA∘−μB∘)(\mu_C^{\circ} + \mu_D^{\circ} - \mu_A^{\circ} - \mu_B^{\circ}) represents the standard Gibbs free energy change for the reaction, ΔG∘\Delta G^{\circ}.

    ΔG∘=∑(νpμp∘)−∑(νrμr∘)\Delta G^{\circ} = \sum (\nu_p \mu_p^{\circ}) - \sum (\nu_r \mu_r^{\circ})

    Combine the logarithmic terms using the properties of logarithms (ln⁡x+ln⁡y=ln⁡(xy)\ln x + \ln y = \ln(xy) and ln⁡x−ln⁡y=ln⁡(x/y)\ln x - \ln y = \ln(x/y)):

    RT[ln⁡(PCP∘)+ln⁡(PDP∘)−ln⁡(PAP∘)−ln⁡(PBP∘)]=RTln⁡[(PCP∘)(PDP∘)(PAP∘)(PBP∘)]RT \left[\ln\left(\frac{P_C}{P^{\circ}}\right) + \ln\left(\frac{P_D}{P^{\circ}}\right) - \ln\left(\frac{P_A}{P^{\circ}}\right) - \ln\left(\frac{P_B}{P^{\circ}}\right)\right] = RT \ln\left[\frac{\left(\frac{P_C}{P^{\circ}}\right)\left(\frac{P_D}{P^{\circ}}\right)}{\left(\frac{P_A}{P^{\circ}}\right)\left(\frac{P_B}{P^{\circ}}\right)}\right]

    The term inside the logarithm is the reaction quotient (QpQ_p) for partial pressures, where the partial pressures are divided by the standard pressure P∘P^{\circ}:

    Qp=(PCP∘)(PDP∘)(PAP∘)(PBP∘)Q_p = \frac{\left(\frac{P_C}{P^{\circ}}\right)\left(\frac{P_D}{P^{\circ}}\right)}{\left(\frac{P_A}{P^{\circ}}\right)\left(\frac{P_B}{P^{\circ}}\right)}

    Since the sum of the stoichiometric coefficients for products (1+1=21+1=2) equals the sum for reactants (1+1=21+1=2), the P∘P^{\circ} terms cancel out in this specific case, simplifying QpQ_p to:

    Qp=PCPDPAPBQ_p = \frac{P_C P_D}{P_A P_B}

    Therefore, the expression for the free energy change for the reaction is:

    ΔG=ΔG∘+RTln⁡Qp\Delta G = \Delta G^{\circ} + RT \ln Q_p
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