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Chemistry

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Answer

0.1416\text{0.1416}

Step-by-step solution

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To explain this to your lecturer, you would present the solution by clearly stating the principles and formulas used at each step.

The problem asks us to determine the fraction of diethyl ether remaining after a specific time, given its half-life for a first-order decomposition reaction.

  1. Determine the rate constant (kk) for the first-order reaction.

    For a first-order reaction, the half-life (t1/2t_{1/2}) is the time required for the concentration of a reactant to decrease to half of its initial value. This is a constant value for a given first-order reaction and is related to the rate constant (kk) by the following equation:

    t1/2=ln⁡(2)kt_{1/2} = \frac{\ln(2)}{k}

    Here, ln⁡(2)\ln(2) is the natural logarithm of 2, which is approximately 0.6931.
    We are given the half-life t1/2=1670 st_{1/2} = 1670 \text{ s}. To find the rate constant kk, we rearrange the formula:

    k=ln⁡(2)t1/2k = \frac{\ln(2)}{t_{1/2}}

    Substitute the given value:

    k=0.69311670 sk = \frac{0.6931}{1670 \text{ s}} k≈0.0004150 s−1k \approx 0.0004150 \text{ s}^{-1}

    This value of kk represents how quickly the reaction proceeds.

  2. Calculate the fraction of diethyl ether remaining after 4710 s4710 \text{ s}.

    To find the amount of reactant remaining after a certain time, we use the integrated rate law for a first-order reaction. This equation relates the concentration of the reactant at time tt ([A]t[A]_t) to its initial concentration ([A]0[A]_0), the rate constant (kk), and the time (tt):

    ln⁡([A]t[A]0)=−kt\ln\left(\frac{[A]_t}{[A]_0}\right) = -kt

    The term [A]t[A]0\frac{[A]_t}{[A]_0} represents the fraction of the reactant remaining at time tt. To solve for this fraction, we need to remove the natural logarithm (ln⁡\ln). We do this by taking the exponential (base ee) of both sides of the equation:

    eln⁡([A]t[A]0)=e−kte^{\ln\left(\frac{[A]_t}{[A]_0}\right)} = e^{-kt}

    This simplifies to:

    [A]t[A]0=e−kt\frac{[A]_t}{[A]_0} = e^{-kt}

    Now, we substitute the calculated rate constant k=0.0004150 s−1k = 0.0004150 \text{ s}^{-1} and the given time t=4710 st = 4710 \text{ s}:

    [A]t[A]0=e−(0.0004150 s−1×4710 s)\frac{[A]_t}{[A]_0} = e^{-(0.0004150 \text{ s}^{-1} \times 4710 \text{ s})}

    First, calculate the product in the exponent:

    0.0004150×4710=1.95450.0004150 \times 4710 = 1.9545

    So, the equation becomes:

    [A]t[A]0=e−1.9545\frac{[A]_t}{[A]_0} = e^{-1.9545}

    Finally, calculate the value:

    [A]t[A]0≈0.1416\frac{[A]_t}{[A]_0} \approx 0.1416

    This means that after 4710 s4710 \text{ s}, approximately 0.1416 (or 14.16%14.16\%) of the initial diethyl ether remains.

    Note: The value 0.750 was not used in these calculations. The constant used in the half-life formula is ln⁡(2)≈0.6931\ln(2) \approx 0.6931.

    The fraction of diethyl ether remaining after 4710 s4710 \text{ s} is approximately 0.1416\boxed{\text{0.1416}}.

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