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Define a transition metal and write the electronic configurations for Mn2+ and Fe2+ ions, explaining why Fe2+ is readily oxidized to Fe3+ but Mn2+ is not readily oxidized to Mn3+.

Chemistry

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SECTION B: INORGANIC CHEMISTRY

3 (a) (i) Define a transition metal.
A transition metal is an element that has a partially filled d subshell in at least one of its common oxidation states. These elements are typically found in the d-block of the periodic table.

3 (a) (ii) Using the box below, write out the electronic configuration for Mn2+^{2+} and Fe2+^{2+} ions (Mn=25, Fe=26).

  • For Fe (Z=26): Ground state is [Ar]3d64s2[Ar] 3d^6 4s^2. Fe2+^{2+} is formed by losing the two 4s electrons, resulting in [Ar]3d6[Ar] 3d^6.
  • For Mn (Z=25): Ground state is [Ar]3d54s2[Ar] 3d^5 4s^2. Mn2+^{2+} is formed by losing the two 4s electrons, resulting in [Ar]3d5[Ar] 3d^5.

Here are the electronic configurations in the 3d orbitals:

\multicolumn5∣c∣3d↑↓↑↑↑↑\begin{array}{|c|c|c|c|c|} \hline \multicolumn{5}{|c|}{\text{3d}} \\ \hline \uparrow \downarrow & \uparrow & \uparrow & \uparrow & \uparrow \\ \hline \end{array} 26Fe2+:(Ar)\text{}_{26}\text{Fe}^{2+} : (\text{Ar}) \multicolumn5∣c∣3d↑↑↑↑↑\begin{array}{|c|c|c|c|c|} \hline \multicolumn{5}{|c|}{\text{3d}} \\ \hline \uparrow & \uparrow & \uparrow & \uparrow & \uparrow \\ \hline \end{array} 25Mn2+:(Ar)\text{}_{25}\text{Mn}^{2+} : (\text{Ar})

3 (b) Account for the fact that Fe2+^{2+} ions are readily oxidized to Fe3+^{3+} ions but Mn2+^{2+} ions are not readily oxidized to Mn3+^{3+} ions.

  1. Determine the electronic configurations of the ions involved.

    • Fe2+^{2+} has an electronic configuration of [Ar]3d6[Ar] 3d^6.
    • Fe3+^{3+} has an electronic configuration of [Ar]3d5[Ar] 3d^5.
    • Mn2+^{2+} has an electronic configuration of [Ar]3d5[Ar] 3d^5.
    • Mn3+^{3+} has an electronic configuration of [Ar]3d4[Ar] 3d^4.
  2. Analyze the stability of the configurations.

    • The 3d53d^5 configuration represents a half-filled d subshell, which is particularly stable due to exchange energy and symmetry.
  3. Explain the oxidation of Fe2+^{2+} to Fe3+^{3+}.

    • Fe2+^{2+} (3d63d^6) readily loses an electron to form Fe3+^{3+} (3d53d^5). This conversion is favorable because it results in the highly stable half-filled 3d53d^5 configuration.
  4. Explain why Mn2+^{2+} is not readily oxidized to Mn3+^{3+}.

    • Mn2+^{2+} already possesses the highly stable half-filled 3d53d^5 configuration. Oxidizing Mn2+^{2+} to Mn3+^{3+} would mean losing an electron from this stable 3d53d^5 configuration to form a less stable 3d43d^4 configuration. This process requires a significant amount of energy and is therefore not readily favorable.

    3 (c) Give the transition metal or transition metal compound used as catalyst in the following conversions.
    The conversions are not visible in the provided image. Please provide the conversions for this part.

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