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Balance the redox reaction between Fe2+ and MnO4^- in acidic solution.
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Step-by-step solution
8 stepsSeparate the reaction into two half-reactions.
Oxidation half-reaction:
Reduction half-reaction:Balance atoms other than oxygen and hydrogen.
For the oxidation half-reaction, Fe atoms are already balanced.
For the reduction half-reaction, Mn atoms are already balanced.
Balance oxygen atoms by adding .
Oxidation: No oxygen atoms.
Reduction: Add to the right side to balance the 4 oxygen atoms on the left.
Balance hydrogen atoms by adding (since the reaction is in acidic medium).
Oxidation: No hydrogen atoms.
Reduction: Add to the left side to balance the 8 hydrogen atoms in on the right.
Balance the charge by adding electrons ().
Oxidation:
Left side charge:
Right side charge:
Add to the right side to balance the charge.Reduction:
Left side charge:
Right side charge:
Add to the left side to balance the charge.Multiply the half-reactions by appropriate integers to equalize the number of electrons.
The oxidation half-reaction has . The reduction half-reaction has .
Multiply the oxidation half-reaction by 5:The reduction half-reaction remains unchanged:
Add the two balanced half-reactions and cancel common species.
Cancel from both sides:
Verify that atoms and charges are balanced.
Atoms:
Mn: 1 on left, 1 on right
O: 4 on left, 4 on right
Fe: 5 on left, 5 on right
H: 8 on left, 8 on right
Charge:
Left side:
Right side:
Both atoms and charges are balanced.The balanced equation is:
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