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Calculate the work done for a reversible isothermal expansion of 1 mole of an ideal gas at 25°C from 10 atm to 5 atm.

Chemistry

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Step 1: Identify given values and convert units.
The number of moles of gas is n=1 moln = 1 \text{ mol}.
The process is reversible and isothermal, meaning the temperature is constant.
The temperature is T=25∘CT = 25^\circ\text{C}. Convert this to Kelvin:

T=25+273.15=298.15 KT = 25 + 273.15 = 298.15 \text{ K}

The gas constant R=8.314 J mol−1 K−1R = 8.314 \text{ J mol}^{-1}\text{ K}^{-1}.

The problem states the gas is "expanded reversibly and isothermally from 5 atm to 10 atm". An expansion implies that the volume increases and the pressure decreases. Therefore, the initial pressure (P1P_1) should be greater than the final pressure (P2P_2). The given pressures "from 5 atm to 10 atm" suggest an increase in pressure, which would be a compression, not an expansion. To be consistent with the term "expanded", we will assume the initial pressure was P1=10 atmP_1 = 10 \text{ atm} and the final pressure was P2=5 atmP_2 = 5 \text{ atm}.

Step 2: Apply the formula for work done in a reversible isothermal process.
For a reversible isothermal process involving an ideal gas, the work done (WW) is given by:

W=−nRTln⁡(V2V1)W = -nRT \ln\left(\frac{V_2}{V_1}\right)

For an isothermal process, P1V1=P2V2P_1V_1 = P_2V_2, which means V2V1=P1P2\frac{V_2}{V_1} = \frac{P_1}{P_2}.
Substituting this into the work equation:

W=−nRTln⁡(P1P2)W = -nRT \ln\left(\frac{P_1}{P_2}\right)

Step 3: Substitute the values and calculate the work done.
Using n=1 moln = 1 \text{ mol}, R=8.314 J mol−1 K−1R = 8.314 \text{ J mol}^{-1}\text{ K}^{-1}, T=298.15 KT = 298.15 \text{ K}, P1=10 atmP_1 = 10 \text{ atm}, and P2=5 atmP_2 = 5 \text{ atm}:

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