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How do you find the factor 'n' to determine the molecular formula from the empirical formula, using an example like CH2 and a molecular mass of 70?

Chemistry

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Answer

You're asking about Step 2 in Problem 1, part b, which determines the factor 'n' to find the molecular formula.

Here's a detailed explanation:

  • Empirical Formula: This is the simplest whole-number ratio of atoms in a compound. For example, if a compound has 2 carbons and 4 hydrogens, its empirical formula is CH2\text{CH}_2.
  • Molecular Formula: This is the actual number of atoms of each element in a molecule of the compound. For the example above, if the actual molecule has 4 carbons and 8 hydrogens, its molecular formula is C4H8\text{C}_4\text{H}_8. Notice that C4H8\text{C}_4\text{H}_8 is (CH2)4(\text{CH}_2)_4.

The molecular formula is always a whole-number multiple of the empirical formula. This whole number is what we call 'n'.

Molecular Formula=(Empirical Formula)n\text{Molecular Formula} = (\text{Empirical Formula})_n

To find 'n', we use the masses:

n=Molecular massEmpirical formula massn = \frac{\text{Molecular mass}}{\text{Empirical formula mass}}

In :

  1. We found the empirical formula in part (a) to be CH2\text{CH}_2.
  2. We calculated the empirical formula mass of CH2\text{CH}_2: (1×12)+(2×1)=14 g/mol(1 \times 12) + (2 \times 1) = 14 \text{ g/mol}.
  3. The problem statement gives the molecular mass as 70 g/mol70 \text{ g/mol}.

So, to find 'n':

n=70 g/mol14 g/mol=5n = \frac{70 \text{ g/mol}}{14 \text{ g/mol}} = 5

This means the actual molecule is 5 times larger than the empirical formula unit. Therefore, the molecular formula is (CH2)5(\text{CH}_2)_5, which simplifies to C5H10\text{C}_5\text{H}_{10}.

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