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When molten Na Hydride (NaH) was electrolysed between inert electrodes, a gas was produced. (1F = 96000C). A-Which substance could the electrode be made up of? B-Identify the gas produced. C-Write an ionic equation for the reaction occurring at the cathode. D-If a current of As A was passed through NaH, for 20 mins. i-Calculate the N° of Faraday used in the experiment ii-The N° of mole of Na atom produced iii-The volume of gas produced at rtp
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3 partsStep 1: Analyze the electrolysis of molten NaH.
Molten sodium hydride () dissociates into ions and ions.
At the cathode (negative electrode), reduction occurs:
At the anode (positive electrode), oxidation occurs:
a) For inert electrodes, materials that do not react with the electrolyte or products are used.
The electrodes could be made of graphite or platinum.
b) The gas produced at the anode is hydrogen gas ().
c) The ionic equation for the reaction occurring at the cathode is:
d) Given:
Current () = 1.5 A
Time () = 20 minutes
Faraday constant () = 96000 C/mol
Molar volume of gas at rtp = 24
i) Calculate the number of Faradays used in the experiment.
First, convert time to seconds:
Next, calculate the total charge () passed:
Now, calculate the number of Faradays:
The number of Faradays used is .
ii) Calculate the number of moles of Na atom produced.
From the cathode reaction: .
1 mole of is produced by 1 mole of electrons (1 Faraday).
The number of moles of Na atom produced is .
iii) Calculate the volume of gas produced at rtp.
From the anode reaction: .
1 mole of gas is produced by 2 moles of electrons (2 Faradays).
At rtp, 1 mole of gas occupies 24 .
The volume of gas produced at rtp is .
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