Step 2: Calculate the mass of air (m).
Using the ideal gas law at state 1: P1V1=mRT1
m=RT1P1V1=(287J/kg\cdotK)×(288.15K)(1.03×105Pa)×(1m3)=82685.05103000≈1.2457kg
Step 3: Calculate the heat flow for each process.
The process consists of two parts:
- Constant pressure heating from T1 to T2.
- Constant volume cooling from T2 to T3, where T3=T1.
Heat flow during constant pressure heating (Q12):
Q12=mcp(T2−T1)
Q12=(1.2457kg)×(1.005kJ/kg\cdotK)×(573.15K−288.15K)
Q12=(1.2457)×(1.005)×(285)=356.59kJ
Heat flow during constant volume cooling (Q23):
Q23=mcv(T3−T2)
Q23=(1.2457kg)×(0.718kJ/kg\cdotK)×(288.15K−573.15K)
Q23=(1.2457)×(0.718)×(−285)=−255.06kJ
Step 4: Calculate the net heat flow (i).
The net heat flow is the sum of heat flows for both processes.
Qnet=Q12+Q23
Qnet=356.59kJ+(−255.06kJ)=101.53kJ
The net heat flow is 101.53kJ.
Step 5: Calculate the change in entropy for each process.
Change in entropy during constant pressure heating (ΔS12):
ΔS12=mcpln(T1T2)
ΔS12=(1.2457kg)×(1.005kJ/kg\cdotK)×ln(288.15K573.15K)
ΔS12=(1.2519885)×ln(1.9891)=(1.2519885)×(0.6877)=0.8611kJ/K
Change in entropy during constant volume cooling (ΔS23):
ΔS23=mcvln(T2T3)
ΔS23=(1.2457kg)×(0.718kJ/kg\cdotK)×ln(573.15K288.15K)
ΔS23=(0.8945)×ln(0.5027)=(0.8945)×(−0.6877)=−0.6150kJ/K
Step 6: Calculate the overall change in entropy (ii).
The overall change in entropy is the sum of entropy changes for both processes.
ΔSoverall=ΔS12+ΔS23
ΔSoverall=0.8611kJ/K+(−0.6150kJ/K)=0.2461kJ/K
The overall change in entropy is 0.2461kJ/K.
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