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A rigid, well-insulated, sealed steel vessel of internal volume 0.30 m³ contains 1.20 kg of wet steam at an initial pressure of 8.5 bar and a dryness fraction of 0.85. The vessel is subsequently cooled until its pressure falls to 2 bar.

Physics

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3 parts
a

0.1911 m3/kg0.1911 \text{ m}^3/\text{kg}

2307.16 kJ/kg2307.16 \text{ kJ/kg}

2768.6 kJ2768.6 \text{ kJ}

b

0.1911 m3/kg0.1911 \text{ m}^3/\text{kg}

0.2148

939.58 kJ/kg939.58 \text{ kJ/kg}

c

−1641.1 kJ-1641.1 \text{ kJ}

Step-by-step solution

10 steps

Part a· 3 steps

Initial state properties

  1. Determine the initial specific volume v1v_1.

    At P1=8.5 barP_1 = 8.5 \text{ bar} and x1=0.85x_1 = 0.85, from saturated steam tables:
    vf=0.001118 m3/kgv_f = 0.001118 \text{ m}^3/\text{kg}
    vg=0.2246 m3/kgv_g = 0.2246 \text{ m}^3/\text{kg}

    v1=vf+x1(vg−vf)v_1 = v_f + x_1 (v_g - v_f) v1=0.001118 m3/kg+0.85(0.2246 m3/kg−0.001118 m3/kg)v_1 = 0.001118 \text{ m}^3/\text{kg} + 0.85 (0.2246 \text{ m}^3/\text{kg} - 0.001118 \text{ m}^3/\text{kg}) v1=0.001118 m3/kg+0.85(0.223482 m3/kg)v_1 = 0.001118 \text{ m}^3/\text{kg} + 0.85 (0.223482 \text{ m}^3/\text{kg}) v1=0.1910777 m3/kg≈0.1911 m3/kgv_1 = 0.1910777 \text{ m}^3/\text{kg} \approx 0.1911 \text{ m}^3/\text{kg}
  2. Determine the initial specific internal energy u1u_1.

    At P1=8.5 barP_1 = 8.5 \text{ bar} and x1=0.85x_1 = 0.85, from saturated steam tables:
    uf=735.0 kJ/kgu_f = 735.0 \text{ kJ/kg}
    ufg=1849.6 kJ/kgu_{fg} = 1849.6 \text{ kJ/kg}

    u1=uf+x1ufgu_1 = u_f + x_1 u_{fg} u1=735.0 kJ/kg+0.85(1849.6 kJ/kg)u_1 = 735.0 \text{ kJ/kg} + 0.85 (1849.6 \text{ kJ/kg}) u1=735.0 kJ/kg+1572.16 kJ/kgu_1 = 735.0 \text{ kJ/kg} + 1572.16 \text{ kJ/kg} u1=2307.16 kJ/kgu_1 = 2307.16 \text{ kJ/kg}
  3. Determine the total internal energy U1U_1.

    Given mass m=1.20 kgm = 1.20 \text{ kg}.

    U1=m⋅u1U_1 = m \cdot u_1 U1=1.20 kg×2307.16 kJ/kgU_1 = 1.20 \text{ kg} \times 2307.16 \text{ kJ/kg} U1=2768.592 kJ≈2768.6 kJU_1 = 2768.592 \text{ kJ} \approx 2768.6 \text{ kJ}

    The initial specific volume is 0.1911 m3/kg\boxed{0.1911 \text{ m}^3/\text{kg}}, the initial specific internal energy is 2307.16 kJ/kg\boxed{2307.16 \text{ kJ/kg}}, and the total internal energy is 2768.6 kJ\boxed{2768.6 \text{ kJ}}.

Part b

0.1911 m3/kg0.1911 \text{ m}^3/\text{kg}

Final state properties

  1. Establish the specific volume at the final state v2v_2.

    Since the vessel is rigid and sealed, the total volume and mass remain constant. Therefore, the specific volume remains constant.

    v2=v1=0.1910777 m3/kg≈0.1911 m3/kgv_2 = v_1 = 0.1910777 \text{ m}^3/\text{kg} \approx 0.1911 \text{ m}^3/\text{kg}
  2. Determine the final dryness fraction x2x_2.

    At P2=2 barP_2 = 2 \text{ bar}, from saturated steam tables:
    vf=0.001061 m3/kgv_f = 0.001061 \text{ m}^3/\text{kg}
    vg=0.8857 m3/kgv_g = 0.8857 \text{ m}^3/\text{kg}

    v2=vf+x2(vg−vf)v_2 = v_f + x_2 (v_g - v_f) 0.1910777=0.001061+x2(0.8857−0.001061)0.1910777 = 0.001061 + x_2 (0.8857 - 0.001061) 0.1900167=x2(0.884639)0.1900167 = x_2 (0.884639) x2=0.19001670.884639≈0.2148x_2 = \frac{0.1900167}{0.884639} \approx 0.2148
  3. Determine the final specific internal energy u2u_2.

    At P2=2 barP_2 = 2 \text{ bar}, from saturated steam tables:
    uf=504.49 kJ/kgu_f = 504.49 \text{ kJ/kg}
    ufg=2024.6 kJ/kgu_{fg} = 2024.6 \text{ kJ/kg}

    u2=uf+x2ufgu_2 = u_f + x_2 u_{fg} u2=504.49 kJ/kg+0.2148(2024.6 kJ/kg)u_2 = 504.49 \text{ kJ/kg} + 0.2148 (2024.6 \text{ kJ/kg}) u2=504.49 kJ/kg+435.09 kJ/kgu_2 = 504.49 \text{ kJ/kg} + 435.09 \text{ kJ/kg} u2=939.58 kJ/kgu_2 = 939.58 \text{ kJ/kg}
  4. Identify the phase region.

    At P2=2 barP_2 = 2 \text{ bar}, vf=0.001061 m3/kgv_f = 0.001061 \text{ m}^3/\text{kg} and vg=0.8857 m3/kgv_g = 0.8857 \text{ m}^3/\text{kg}.
    Since vf<v2<vgv_f < v_2 < v_g (0.001061<0.1911<0.88570.001061 < 0.1911 < 0.8857), the steam is in the wet vapor region.
    The specific volume at the final state is 0.1911 m3/kg\boxed{0.1911 \text{ m}^3/\text{kg}}, the final dryness fraction is 0.2148\boxed{0.2148}, and the final specific internal energy is 939.58 kJ/kg\boxed{939.58 \text{ kJ/kg}}. The phase region is wet vapor.

Part c

−1641.1 kJ-1641.1 \text{ kJ}

Heat transfer during cooling

  1. Apply the First Law of Thermodynamics.

    For a closed system with a rigid vessel, work W=0W=0. The First Law simplifies to Q=ΔU=U2−U1Q = \Delta U = U_2 - U_1.

  2. Calculate the total internal energy at the final state U2U_2.

    U2=m⋅u2U_2 = m \cdot u_2 U2=1.20 kg×939.58 kJ/kgU_2 = 1.20 \text{ kg} \times 939.58 \text{ kJ/kg} U2=1127.496 kJ≈1127.5 kJU_2 = 1127.496 \text{ kJ} \approx 1127.5 \text{ kJ}
  3. Calculate the heat transfer QQ.

    Q=U2−U1Q = U_2 - U_1 Q=1127.496 kJ−2768.592 kJQ = 1127.496 \text{ kJ} - 2768.592 \text{ kJ} Q=−1641.096 kJ≈−1641.1 kJQ = -1641.096 \text{ kJ} \approx -1641.1 \text{ kJ}

    The negative sign indicates that heat is rejected by the steam.
    The heat transfer during cooling is −1641.1 kJ\boxed{-1641.1 \text{ kJ}}. Heat is rejected by the steam, as indicated by the negative sign, meaning energy is leaving the system.

Part d

P-v diagram and explanation

P-v Diagram\text{P-v Diagram}

(Imagine a P-v diagram with a saturation dome.
Point 1: Located within the saturation dome at P1=8.5 barP_1 = 8.5 \text{ bar} and v1=0.1911 m3/kgv_1 = 0.1911 \text{ m}^3/\text{kg}.
Point 2: Located vertically below Point 1, also within the saturation dome, at P2=2 barP_2 = 2 \text{ bar} and v2=0.1911 m3/kgv_2 = 0.1911 \text{ m}^3/\text{kg}.
A vertical line connects Point 1 to Point 2, representing the constant specific volume process.)

Pressure and temperature can change even though the vessel volume remains constant because the system is undergoing a phase change (from wet steam at higher pressure/temperature to wet steam at lower pressure/temperature) due to heat rejection. As heat is removed, the internal energy of the steam decreases. In the saturation region, pressure and temperature are directly related; a decrease in internal energy at constant volume leads to a decrease in both pressure and temperature as some vapor condenses into liquid.

Part e

Evaluation of ideal gas assumption

Treating steam as an ideal gas is incorrect because steam, especially when it is a wet vapor mixture, does not behave as an ideal gas. The ideal gas law assumes negligible molecular volume and intermolecular forces, which are not valid for water vapor, particularly near saturation conditions or during phase changes. The constant-volume ideal-gas relation (P1/T1=P2/T2P_1/T_1 = P_2/T_2) is based on these flawed assumptions for steam and would yield inaccurate results. Steam tables are the more appropriate property source because they are derived from experimental data and accurately account for the real behavior of water and steam across all phases, including the complex interactions during phase transitions.

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