Activation energy equation

Physics

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The activation energy equation is typically represented by the Arrhenius equation, which relates the rate constant of a reaction to the activation energy and temperature.

k=Ae−Ea/(RT)k = A e^{-E_a / (RT)}

Where:

  • kk is the rate constant
  • AA is the pre-exponential factor or frequency factor
  • EaE_a is the activation energy
  • RR is the universal gas constant (8.314 J⋅mol−1⋅K−18.314 \text{ J}\cdot\text{mol}^{-1}\cdot\text{K}^{-1})
  • TT is the absolute temperature in Kelvin

The activation energy (EaE_a) can be isolated from this equation:

Ea=−RTln⁡(kA)E_a = -RT \ln\left(\frac{k}{A}\right)

Or, more commonly, by comparing rate constants at two different temperatures:

ln⁡(k2k1)=EaR(1T1−1T2)\ln\left(\frac{k_2}{k_1}\right) = \frac{E_a}{R} \left(\frac{1}{T_1} - \frac{1}{T_2}\right)

This equation allows for the calculation of the activation energy if the rate constants at two different temperatures are known.

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