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An organic compound contains 59.0% C, 7.15% H, 26.20% O, and 7.65% N and has a molar mass of 183 g/mol. What is its molecular formula? (Take C = 12, O = 16, H = 1, N = 14) N.B: Show all working

Chemistry

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Answers

3 parts
1

C9H13O3NC_9H_{13}O_3N

2

molecular formula\text{molecular formula}

3

C4H5N2OC_4H_5N_2O

Step-by-step solution

9 steps

Here are the solutions to the questions:

Part 1· 6 steps

Molecular Formula

To find the molecular formula, we follow these steps:

  1. Convert percentages to grams (assuming a 100 g sample) and then to moles.

    • For Carbon (C): Moles of C=59.0 g12 g/mol=4.917 mol\text{Moles of C} = \frac{59.0\, \text{g}}{12\, \text{g/mol}} = 4.917\, \text{mol}
    • For Hydrogen (H): Moles of H=7.15 g1 g/mol=7.150 mol\text{Moles of H} = \frac{7.15\, \text{g}}{1\, \text{g/mol}} = 7.150\, \text{mol}
    • For Oxygen (O): Moles of O=26.20 g16 g/mol=1.638 mol\text{Moles of O} = \frac{26.20\, \text{g}}{16\, \text{g/mol}} = 1.638\, \text{mol}
    • For Nitrogen (N): Moles of N=7.65 g14 g/mol=0.546 mol\text{Moles of N} = \frac{7.65\, \text{g}}{14\, \text{g/mol}} = 0.546\, \text{mol}
  2. Divide by the smallest number of moles to find the mole ratio.

    The smallest number of moles is 0.546 mol0.546\, \text{mol} (for N).

    • For C: 4.9170.546≈9.00\frac{4.917}{0.546} \approx 9.00
    • For H: 7.1500.546≈13.09≈13\frac{7.150}{0.546} \approx 13.09 \approx 13
    • For O: 1.6380.546≈3.00\frac{1.638}{0.546} \approx 3.00
    • For N: 0.5460.546=1.00\frac{0.546}{0.546} = 1.00
  3. Write the empirical formula based on these ratios.

    The empirical formula is C9H13O3NC_9H_{13}O_3N.

  4. Calculate the empirical formula mass.

    Empirical formula mass=(9×12)+(13×1)+(3×16)+(1×14)\text{Empirical formula mass} = (9 \times 12) + (13 \times 1) + (3 \times 16) + (1 \times 14) =108+13+48+14=183 g/mol= 108 + 13 + 48 + 14 = 183\, \text{g/mol}
  5. Determine the ratio of the molar mass to the empirical formula mass.

    n=Molar massEmpirical formula mass=183 g/mol183 g/mol=1n = \frac{\text{Molar mass}}{\text{Empirical formula mass}} = \frac{183\, \text{g/mol}}{183\, \text{g/mol}} = 1
  6. Multiply the subscripts in the empirical formula by nn to get the molecular formula.

    Since n=1n=1, the molecular formula is the same as the empirical formula.

    The molecular formula is C9H13O3N\boxed{C_9H_{13}O_3N}.

Part 2

molecular formula\text{molecular formula}

Definition of Molecular Formula

A chemical formula that shows the actual number and kinds of atoms present in one molecule of a compound is called a molecular formula.

The answer is molecular formula\boxed{\text{molecular formula}}.

Part 3

C4H5N2OC_4H_5N_2O

Empirical Formula

To find the empirical formula from the molecular formula C8H10N4O2C_8H_{10}N_4O_2, we need to find the simplest whole-number ratio of the atoms.

  1. Identify the subscripts for each element

    C=8, H=10, N=4, O=2.

  2. Find the greatest common divisor (GCD) of these subscripts.

    The GCD of 8, 10, 4, and 2 is 2.

  3. Divide each subscript by the GCD.

    • For C: 8÷2=48 \div 2 = 4
    • For H: 10÷2=510 \div 2 = 5
    • For N: 4÷2=24 \div 2 = 2
    • For O: 2÷2=12 \div 2 = 1

    The empirical formula is C4H5N2O\boxed{C_4H_5N_2O}.

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