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By which formula the molal elevation constant (Kb) can be calculated

Chemistry

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Q.1 (viii) By which formula the molal elevation constant (Kb) can be calculated

  1. Recall the formula for elevation in boiling point.

    The elevation in boiling point (ΔTb\Delta T_b) is given by:

    ΔTb=Kb×m\Delta T_b = K_b \times m

    where KbK_b is the molal elevation constant and mm is the molality of the solution.

  2. Express molality (mm) in terms of mass and molar mass.

    Molality (mm) is defined as moles of solute per kilogram of solvent.

    m=moles of solutemass of solvent (in kg)m = \frac{\text{moles of solute}}{\text{mass of solvent (in kg)}}

    If WsW_s is the mass of the solute, MrM_r is the molar mass of the solute, and WwW_w is the mass of the solvent in grams, then:

    Moles of solute=WsMr\text{Moles of solute} = \frac{W_s}{M_r} Mass of solvent (in kg)=Ww1000\text{Mass of solvent (in kg)} = \frac{W_w}{1000}

    So,

    m=Ws/MrWw/1000=Ws×1000Mr×Wwm = \frac{W_s / M_r}{W_w / 1000} = \frac{W_s \times 1000}{M_r \times W_w}
  3. Substitute the expression for molality into the boiling point elevation formula and rearrange for KbK_b.

    ΔTb=Kb×Ws×1000Mr×Ww\Delta T_b = K_b \times \frac{W_s \times 1000}{M_r \times W_w}

    Rearranging to solve for KbK_b:

    Kb=ΔTb×Mr×Ww1000×WsK_b = \frac{\Delta T_b \times M_r \times W_w}{1000 \times W_s}

    Comparing this with the given options, option (a) matches this formula.

    The final answer is (a) Mr×ΔTb×Ww1000×Ws\boxed{\text{(a) } \frac{M_r \times \Delta T_b \times W_w}{1000 \times W_s}}.

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