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Draw and name the structure of polymer formed from propene. Write an ionic equation for the reaction between sodium sulphate solution and lead (II) nitrate solution.

Chemistry

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15. (b) Draw and name the structure of polymer formed from propene.
Propene is CH2=CH−CH3\text{CH}_2=\text{CH}-\text{CH}_3. During polymerization, the double bond breaks, and the monomers link together to form polypropene.

The repeating unit of polypropene is:

CH3∣−CH2−CH−n\begin{matrix} & \text{CH}_3 \\ & | \\ - & \text{CH}_2 & - & \text{CH} & - \end{matrix}_n

The name of the polymer is Polypropene\boxed{\text{Polypropene}}.

16. (a) Write an ionic equation for the reaction between sodium sulphate solution and lead (II) nitrate solution.
The reaction is between lead (II) nitrate (Pb(NO3)2\text{Pb(NO}_3)_2) and sodium sulphate (Na2SO4\text{Na}_2\text{SO}_4) to form lead (II) sulphate (PbSO4\text{PbSO}_4) precipitate and sodium nitrate (NaNO3\text{NaNO}_3).

Pb(NO3)2(aq)+Na2SO4(aq)⟶PbSO4(s)+2NaNO3(aq)\text{Pb(NO}_3)_2 \text{(aq)} + \text{Na}_2\text{SO}_4 \text{(aq)} \longrightarrow \text{PbSO}_4 \text{(s)} + 2\text{NaNO}_3 \text{(aq)}

The full ionic equation is:

Pb2+(aq)+2NO3−(aq)+2Na+(aq)+SO42−(aq)⟶PbSO4(s)+2Na+(aq)+2NO3−(aq)\text{Pb}^{2+} \text{(aq)} + 2\text{NO}_3^- \text{(aq)} + 2\text{Na}^+ \text{(aq)} + \text{SO}_4^{2-} \text{(aq)} \longrightarrow \text{PbSO}_4 \text{(s)} + 2\text{Na}^+ \text{(aq)} + 2\text{NO}_3^- \text{(aq)}

The net ionic equation, removing spectator ions, is:

Pb2+(aq)+SO42−(aq)⟶PbSO4(s)\boxed{\text{Pb}^{2+} \text{(aq)} + \text{SO}_4^{2-} \text{(aq)} \longrightarrow \text{PbSO}_4 \text{(s)}}

(b) Determine the mass of the lead salt formed in the reaction in (a) above.
The lead salt formed is lead (II) sulphate (PbSO4\text{PbSO}_4). The initial lead powder (0.63 g) is converted entirely into Pb2+\text{Pb}^{2+} ions, which then form PbSO4\text{PbSO}_4.

  1. Calculate the molar mass of lead (Pb).

    Given Pb=207\text{Pb} = 207.
    Molar mass of Pb=207 g/mol\text{Pb} = 207 \text{ g/mol}.

  2. Calculate the moles of lead (Pb) from the initial sample.

    Moles of Pb=Mass of PbMolar mass of Pb=0.63 g207 g/mol\text{Moles of Pb} = \frac{\text{Mass of Pb}}{\text{Molar mass of Pb}} = \frac{0.63 \text{ g}}{207 \text{ g/mol}}
  3. Determine the moles of lead (II) sulphate (PbSO4\text{PbSO}_4) formed.

    From the ionic equation, 1 mole of Pb2+\text{Pb}^{2+} produces 1 mole of PbSO4\text{PbSO}_4.
    So, Moles of PbSO4=Moles of Pb=0.63207 mol\text{Moles of PbSO}_4 = \text{Moles of Pb} = \frac{0.63}{207} \text{ mol}.

  4. Calculate the molar mass of lead (II) sulphate (PbSO4\text{PbSO}_4).

    Given Pb=207\text{Pb} = 207, S=32\text{S} = 32, O=16\text{O} = 16.

    Molar mass of PbSO4=207+32+(4×16)=207+32+64=303 g/mol\text{Molar mass of PbSO}_4 = 207 + 32 + (4 \times 16) = 207 + 32 + 64 = 303 \text{ g/mol}
  5. Calculate the mass of lead (II) sulphate (PbSO4\text{PbSO}_4) formed.

    Mass of PbSO4=Moles of PbSO4×Molar mass of PbSO4\text{Mass of PbSO}_4 = \text{Moles of PbSO}_4 \times \text{Molar mass of PbSO}_4 Mass of PbSO4=0.63207 mol×303 g/mol\text{Mass of PbSO}_4 = \frac{0.63}{207} \text{ mol} \times 303 \text{ g/mol} Mass of PbSO4=190.89207 g\text{Mass of PbSO}_4 = \frac{190.89}{207} \text{ g} Mass of PbSO4=0.92217... g\text{Mass of PbSO}_4 = 0.92217... \text{ g}

    The mass of the lead salt formed is 0.922 g\boxed{0.922 \text{ g}} (to 3 significant figures).

    17. For each of the following experiments, give the observations and the type of change that occurs (temporary physical or temporary chemical).

    | Experiment | Observation

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