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Write the expression for the equilibrium constant K c for the synthesis of ammonia reaction: N 2(g) + 3H 2(g) ⇌ 2NH 3(g)

Chemistry

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Answer

[NH3]2[N2][H2]3\frac{[\text{NH}_3]^2}{[\text{N}_2][\text{H}_2]^3}

Step-by-step solution

3 steps
  1. Identify the given reversible reaction.

    The given reaction is the synthesis of ammonia:

    N2(g)+3H2(g)⇌2NH3(g)\text{N}_2\text{(g)} + 3\text{H}_2\text{(g)} \rightleftharpoons 2\text{NH}_3\text{(g)}
  2. Write the general expression for the equilibrium constant KcK_c.

    For a general reversible reaction aA+bB⇌cC+dDa\text{A} + b\text{B} \rightleftharpoons c\text{C} + d\text{D}, the equilibrium constant KcK_c is given by:

    Kc=[C]c[D]d[A]a[B]bK_c = \frac{[\text{C}]^c[\text{D}]^d}{[\text{A}]^a[\text{B}]^b}

    where [X][\text{X}] represents the molar concentration of species X at equilibrium, and a,b,c,da, b, c, d are the stoichiometric coefficients.

  3. Substitute the concentrations of reactants and products with their stoichiometric coefficients into the KcK_c expression.

    For the reaction N2(g)+3H2(g)⇌2NH3(g)\text{N}_2\text{(g)} + 3\text{H}_2\text{(g)} \rightleftharpoons 2\text{NH}_3\text{(g)}:

    • Products: NH3\text{NH}_3 with a coefficient of 2.
    • Reactants: N2\text{N}_2 with a coefficient of 1, and H2\text{H}_2 with a coefficient of 3.

    Therefore, the KcK_c expression is:

    Kc=[NH3]2[N2]1[H2]3K_c = \frac{[\text{NH}_3]^2}{[\text{N}_2]^1[\text{H}_2]^3} Kc=[NH3]2[N2][H2]3K_c = \boxed{\frac{[\text{NH}_3]^2}{[\text{N}_2][\text{H}_2]^3}}
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