Step 1: Calculate the molar mass of KNO3.
M(KNO3)=M(K)+M(N)+3×M(O)
M(KNO3)=39.0+14.0+(3×16.0)=39.0+14.0+48.0=101.0 g/mol
Step 2: Calculate the number of moles of KNO3.
Moles of KNO3=MolarmassofKNO3MassofKNO3
Moles of KNO3=101.0g/mol15.6g≈0.15446 mol
Step 3: Convert the volume of the solution from cm3 to dm3.
1dm3=1000cm3
Volume=60cm3=100060dm3=0.060dm3
Step 4: Calculate the solubility of KNO3 in mol dm−3.
Solubility=VolumeofsolutionMolesofKNO3
Solubility=0.060dm30.15446mol≈2.57moldm−3
- b) (ii) The solubility of KNO3 is 2.57moldm−3.
Step 5: Outline the preparation of PbCl2(s) from Pb(NO3)2 and a mineral acid.
- c) (i) To prepare PbCl2(s), mix an aqueous solution of lead(II) nitrate (Pb(NO3)2) with a mineral acid containing chloride ions, such as hydrochloric acid (HCl). Lead(II) chloride will precipitate out as a solid. Filter the precipitate, wash it with distilled water, and then dry it.
Step 6: Write an equation for the reaction in 2(c)(i).
- c) (ii) Pb(NO3)2(aq)+2HCl(aq)→PbCl2(s)+2HNO3(aq)
Step 7: Give the reason for copper's electron configuration.
- d) (i) The electron configuration of copper is 1s22s22p63s23p63d104s1 because a completely filled d-subshell (3d10) is more stable than a partially filled d-subshell (3d9). One electron from the 4s orbital is promoted to the 3d orbital to achieve this greater stability.
Step 8: Mention the two oxidation states of iron in its chlorides.
- d) (ii) The two oxidation states of iron in its chlorides are +2 (in FeCl2) and +3 (in FeCl3).
Step 9: Name one chemical process in which iron is used as a catalyst.
- d) (iii) Iron is used as a catalyst in the Haberprocess (for the synthesis of ammonia).
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