To calculate the maximum mass of hydrated sodium sulfate crystals, we need to follow these steps:
Step 1: Calculate the moles of sodium hydroxide (NaOH) used.
The volume of NaOH is 25.0cm3, which needs to be converted to dm3.
Volume=25.0cm3×1000cm31dm3=0.0250dm3
Now, calculate the moles of NaOH:
MolesofNaOH=Concentration×Volume
MolesofNaOH=1.60mol/dm3×0.0250dm3=0.0400mol
Step 2: Determine the mole ratio from the balanced chemical equation and calculate the moles of hydrated sodium sulfate (Na2SO4⋅10H2O) formed.
The balanced equation is:
2NaOH(aq)+H2SO4(aq)+8H2O(l)→Na2SO4⋅10H2O(s)
From the equation, 2 moles of NaOH produce 1 mole of Na2SO4⋅10H2O.
MolesofNa2SO4⋅10H2O=21×MolesofNaOH
MolesofNa2SO4⋅10H2O=21×0.0400mol=0.0200mol
Step 3: Calculate the molar mass of hydrated sodium sulfate (Na2SO4⋅10H2O).
Using atomic masses: Na=22.99 g/mol, S=32.07 g/mol, O=16.00 g/mol, H=1.008 g/mol.
MolarmassofNa2SO4⋅10H2O=(2×22.99)+32.07+(4×16.00)+10×((2×1.008)+16.00)
=45.98+32.07+64.00+10×(2.016+16.00)
=142.05+10×18.016
=142.05+180.16
=322.21g/mol
Step 4: Calculate the maximum mass of hydrated sodium sulfate crystals.
Mass=Moles×Molarmass
MassofNa2SO4⋅10H2O=0.0200mol×322.21g/mol
MassofNa2SO4⋅10H2O=6.4442g
Rounding to three significant figures (based on the given data 25.0cm3 and 1.60mol/dm3):
MassofNa2SO4⋅10H2O=6.44 g
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