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Calculate the oxidation number of sulphur in H₂S₂O₈.

Chemistry

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20. a) Calculate the oxidation number of sulphur in H₂S₂O₈. [1]

Step 1: Assign known oxidation numbers.
In H2S2O8\text{H}_2\text{S}_2\text{O}_8, hydrogen has an oxidation number of +1+1, and oxygen usually has −2-2. However, H2S2O8\text{H}_2\text{S}_2\text{O}_8 (peroxydisulfuric acid) contains a peroxide linkage (−O−O−)(-\text{O}-\text{O}-), where two oxygen atoms have an oxidation number of −1-1. The remaining six oxygen atoms have an oxidation number of $-2

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