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Give the reason why the electron configuration of copper is 1s2 2s2 2p6 3s2 3p6 3d10 4s1 and not 1s2 2s2 2p6 3s2 3p6 3d9 4s2.

Chemistry

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2 parts
ii

+2 and +3\text{+2 and +3}

iii

Haber process\text{Haber process}

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Part i· 2 steps

Give the reason why the electron configuration of copper is 1s22s22p63s23p63d104s11s^2 2s^2 2p^6 3s^2 3p^6 3d^{10} 4s^1 and not 1s22s22p63s23p63d94s21s^2 2s^2 2p^6 3s^2 3p^6 3d^9 4s^2.

  1. Identify the principle of stability.

    The electron configuration 1s22s22p63s23p63d104s11s^2 2s^2 2p^6 3s^2 3p^6 3d^{10} 4s^1 is preferred because a fully filled 3d103d^{10} subshell is more stable than a partially filled 3d93d^9 subshell.

  2. Explain the electron promotion.

    One electron from the 4s4s orbital is promoted to the 3d3d orbital to achieve this more stable, fully filled 3d103d^{10} configuration.

Part ii

+2 and +3\text{+2 and +3}

Mention the two oxidation states of iron in its chlorides.

  1. Identify common iron chlorides.

    Iron forms two common chlorides: iron(II) chloride (FeCl2FeCl_2) and iron(III) chloride (FeCl3FeCl_3).

  2. Determine the oxidation states.

    In FeCl2FeCl_2, the oxidation state of iron is +2. In FeCl3FeCl_3, the oxidation state of iron is +3.
    The two oxidation states are +2 and +3\boxed{\text{+2 and +3}}.

Part iii

Haber process\text{Haber process}

Name one chemical process in which iron is used as a catalyst.

  1. Recall industrial processes using iron as a catalyst.

    Iron is used as a catalyst in the Haber process.
    The chemical process is the Haber process\boxed{\text{Haber process}}.

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