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Study the reaction scheme below and answer the questions which follow. (i) Give the reagents and reaction conditions for the steps represented by i to iv. (ii) Give the structures of compounds A to D.
Chemistry
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6. (a) Study the reaction scheme below and answer the questions which follow.
(i) Give the reagents and reaction conditions for the steps represented by i to iv.
| Step | Reagent(s) | Reaction conditions |
|---|---|---|
| i | Alcoholic KOH | Heat (reflux) |
| ii | HBr | Room temperature |
| iii | Aqueous KOH | Heat (reflux) |
| iv | HCl | Room temperature |
(ii) Give the structures of compounds A to D.
Based on the reaction scheme:
- Compound D is explicitly given as CH(CH)OH (1-butanol).
- Step iii is the conversion of A (CHBr) to D (1-butanol). This is a nucleophilic substitution where Br is replaced by OH. Therefore, A must be 1-bromobutane.
- Step i is the conversion of A (1-bromobutane) to B (CH). This is an elimination reaction, forming an alkene. Thus, B is but-1-ene.
- Step ii is the conversion of B (but-1-ene) to C (CHBr). This is the addition of HBr to an alkene. According to Markovnikov's rule, the major product is 2-bromobutane.
A: (1-bromobutane)
B: (But-1-ene)
C: (2-bromobutane)
D: $\boxed{CH_3CH_2CH_2\text
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