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What are the products of reduction for but-2-enal using Na/NH3 and H2/Raney Ni?
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3 partsStep-by-step solution
6 stepslet's determine the products of reduction for the given molecule, which is but-2-enal (), using different reducing agents. This molecule contains both an alkene () double bond and an aldehyde () functional group.
Starting molecule: But-2-enal
Part a· 2 steps
Using (Sodium in liquid ammonia)
This is a Birch reduction condition. For -unsaturated aldehydes, selectively reduces the carbon-carbon double bond () while leaving the aldehyde () group intact.
Identify the functional groups to be reduced.
The double bond will be reduced.
Add hydrogen atoms across the double bond.
Product: Butanal
Part b
Using /Raney Ni (Hydrogen with Raney Nickel catalyst)
Raney Nickel is a powerful, non-selective hydrogenation catalyst. It will reduce both carbon-carbon double bonds () and aldehyde () groups. The aldehyde will be reduced to a primary alcohol.
Identify the functional groups to be reduced.
Both the double bond and the group will be reduced.
Add hydrogen atoms across the double bond and convert the aldehyde to an alcohol.
Product: Butan-1-ol
Part c
Using (Sodium borohydride)
Sodium borohydride is a mild and selective reducing agent. It reduces aldehydes and ketones to alcohols but does not reduce carbon-carbon double bonds ().
Identify the functional groups to be reduced.
Only the aldehyde () group will be reduced.
Convert the aldehyde to a primary alcohol, leaving the double bond untouched.
Product: But-2-en-1-ol
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