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What is the main product of the reduction of ethyl ethanoate with lithium aluminum hydride?

Chemistry

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Answer

A. ethanol\text{A. ethanol}

Step-by-step solution

3 steps

A. ethanol

  1. Identify the reactant and reagent.

    The reactant is ethyl ethanoate, which is an ester with the formula CH3COOCH2CH3\text{CH}_3\text{COOCH}_2\text{CH}_3.
    The reagent is lithium aluminum hydride (LiAlH4\text{LiAlH}_4), a strong reducing agent.

  2. Understand the reaction of esters with LiAlH4\text{LiAlH}_4.

    LiAlH4\text{LiAlH}_4 reduces esters to primary alcohols. The ester linkage (-COO-\text{-COO-}) is cleaved, and both the acyl part and the alkoxy part are reduced to alcohols.

  3. Determine the products of the reduction.

    The acyl part (CH3CO−\text{CH}_3\text{CO}-) of ethyl ethanoate is reduced to ethanol (CH3CH2OH\text{CH}_3\text{CH}_2\text{OH}).
    The alkoxy part (−OCH2CH3-\text{OCH}_2\text{CH}_3) of ethyl ethanoate is also reduced to ethanol (CH3CH2OH\text{CH}_3\text{CH}_2\text{OH}).

    The overall reaction is:

    CH3COOCH2CH3→1. LiAlH4 2. H2O2CH3CH2OH\text{CH}_3\text{COOCH}_2\text{CH}_3 \xrightarrow{\text{1. LiAlH}_4 \text{ 2. H}_2\text{O}} 2\text{CH}_3\text{CH}_2\text{OH}

    Therefore, the product obtained is ethanol.

    The final answer is A. ethanol\text{A. ethanol}.

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