This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.
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Here are the answers to your questions: Pre laboratory questions: 1. Why is the solution boiled after the initial colour change during titration? The solution is boiled to expel dissolved carbon dioxide (CO_2). During the titration of sodium carbonate with hydrochloric acid, carbonic acid (H_2CO_3) is formed, which then decomposes to CO_2 and water. Dissolved CO_2 forms carbonic acid, a weak acid, which can interfere with the indicator's color change and lead to an inaccurate endpoint. Boiling removes the CO_2, ensuring a sharper and more accurate endpoint. 2. What properties make sodium carbonate (Na_2CO_3) suitable as a primary standard substance? Sodium carbonate is suitable as a primary standard because it possesses several key properties: • It can be obtained in a high state of purity. • It is stable in air after drying, meaning it does not readily absorb moisture (non-hygroscopic) or react with atmospheric CO_2. • It has a relatively high molar mass (105.99 g/mol), which minimizes the percentage error in weighing. • It is readily soluble in water and reacts stoichiometrically with acids. Post laboratory questions: 1. Why is methyl orange more appropriate than phenolphthalein for this acid-base titration? This titration involves a weak base (Na_2CO_3) and a strong acid (HCl). The equivalence point for such a titration occurs in the acidic pH range (approximately pH 3.7-4.0 for the complete neutralization of Na_2CO_3 to H_2CO_3/CO_2). Methyl orange has a pH indicator range of 3.1-4.4, which closely matches this acidic equivalence point. Phenolphthalein, with a pH range of 8.2-10.0, would indicate the first equivalence point (carbonate to bicarbonate) but would change color too early for the complete neutralization, leading to an inaccurate result for the overall reaction. 2. Why must concordant titre values be obtained in volumetric analysis before calculating results? Concordant titre values are essential because they demonstrate the precision and reproducibility of the experimental measurements. By obtaining multiple titre values that are very close to each other (e.g., within ± 0.1 mL), it indicates that random errors have been minimized and that the experimental technique is consistent. Averaging these concordant values provides a more reliable and accurate representation of the true volume of titrant required, thus ensuring the validity of the final calculated results.