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The solution provides answers to questions about the hydrolysis of a triglyceride, preparation of ethyne, and addition polymerization of perspex. What are the original questions?

Chemistry

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6. (b) (ii) G is completely hydrolysed by heating with aqueous sodium hydroxide.

  • (I) Give the structural formula of the alcohol formed. The alcohol formed from the hydrolysis of a triglyceride is glycerol (propane-1,2,3-triol). HOCH2CH(OH)CH2OH\text{HOCH}_2\text{CH(OH)CH}_2\text{OH}
  • (II) Write a formula for the sodium salt formed. Assuming compound G is a tri-ester of stearic acid, the sodium salt formed is sodium stearate. CH3(CH2)16COONa\text{CH}_3(\text{CH}_2)_{16}\text{COONa}
  • (III) State the use of the sodium salt. Cleansing agent (soap)

6. (c) Ethyne is the first member of the alkyne family.

  • (i) Name two reagents that can be used in the laboratory to prepare the gas.
    • Calcium carbide (CaC2\text{CaC}_2)
    • Water (H2O\text{H}_2\text{O})
  • (ii) Write an equation for the reaction. CaC2(s)+2H2O(l)→Ca(OH)2(aq)+C2H2(g)\text{CaC}_2(s) + 2\text{H}_2\text{O}(l) \rightarrow \text{Ca(OH)}_2(aq) + \text{C}_2\text{H}_2(g)

6. (d) Perspex is an addition synthetic polymer formed from the monomer,
The monomer is methyl methacrylate: CH2=C(CH3)(COOCH3)\text{CH}_2=\text{C}(\text{CH}_3)(\text{COOCH}_3).

  • (i) What is meant by addition polymerisation? Addition polymerisation is a process where unsaturated monomers (containing double or triple bonds) join together without the loss of any atoms, forming a long chain polymer.

  • (ii) Draw three repeat units of Perspex. The repeat unit is [−CH2−C(CH3)(COOCH3)−][-\text{CH}_2-\text{C}(\text{CH}_3)(\text{COOCH}_3)-]. Three repeat units are:

    [CH3∣−CH2−C−∣COOCH3][CH3∣−CH2−C−∣COOCH3][CH3∣−CH2−C−∣COOCH3]\begin{bmatrix} \text{CH}_3 \\ | \\ -\text{CH}_2-\text{C}- \\ | \\ \text{COOCH}_3 \end{bmatrix} \begin{bmatrix} \text{CH}_3 \\ | \\ -\text{CH}_2-\text{C}- \\ | \\ \text{COOCH}_3 \end{bmatrix} \begin{bmatrix} \text{CH}_3 \\ | \\ -\text{CH}_2-\text{C}- \\ | \\ \text{COOCH}_3 \end{bmatrix}
  • (iii) Give one use of Perspex. Making lenses (e.g., in spectacles or aircraft windows)

6. (e) State two environmental hazards associated with synthetic polymers.

  • Non-biodegradability: Synthetic polymers do not decompose naturally, leading to persistent waste accumulation in landfills and oceans.
  • Pollution during incineration: Burning synthetic polymers can release toxic gases and contribute to air pollution.
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