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Locate 70°C on the x-axis.

Mathematics

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20. a) Which salt is more soluble in water at 70°C?

  1. Locate 70°C on the x-axis.

  2. Read the solubility for Salt A and Salt B at 70°C from the graph.

    At 70°C, Salt A has a solubility of approximately 48 g per 100 g of H₂O.
    At 70°C, Salt B has a solubility of approximately 52 g per 100 g of H₂O.

  3. Compare the solubilities.

    Salt B has a higher solubility at 70°C.
    The more soluble salt is:

    Salt B\boxed{\text{Salt B}}

    20. b) What is the amount of salt in 50g of saturated solution of salt A at 120°C?

  4. Determine the solubility of Salt A at 120°C from the graph.

    At 120°C, the solubility of Salt A is approximately 75 g per 100 g of H₂O.

  5. Calculate the mass of the saturated solution formed by 100 g of water.

    Mass of saturated solution = Mass of Salt A + Mass of water
    Mass of saturated solution = 75 g+100 g=175 g75 \text{ g} + 100 \text{ g} = 175 \text{ g}

  6. Calculate the amount of salt in 50 g of saturated solution.

    Mass of Salt A=Mass of Salt A in 175 g solutionMass of 175 g solution×Desired mass of solution\text{Mass of Salt A} = \frac{\text{Mass of Salt A in 175 g solution}}{\text{Mass of 175 g solution}} \times \text{Desired mass of solution} Mass of Salt A=75 g175 g×50 g\text{Mass of Salt A} = \frac{75 \text{ g}}{175 \text{ g}} \times 50 \text{ g} Mass of Salt A=37×50 g\text{Mass of Salt A} = \frac{3}{7} \times 50 \text{ g} Mass of Salt A=1507 g\text{Mass of Salt A} = \frac{150}{7} \text{ g} Mass of Salt A≈21.43 g\text{Mass of Salt A} \approx 21.43 \text{ g}

    The amount of salt in 50g of saturated solution of salt A at 120°C is:

    21.43 g\boxed{21.43 \text{ g}}

    21. a) Identify solid P.
    Solid P is formed by the reaction of dry chlorine gas with iron wire. This reaction produces iron(III) chloride.

    Iron(III) chloride\boxed{\text{Iron(III) chloride}}

    21. b) Write an equation for formation of solid P.
    The balanced chemical equation for the formation of iron(III) chloride from iron and chlorine gas is:

    2Fe(s)+3Cl2(g)→2FeCl3(s)\boxed{2\text{Fe(s)} + 3\text{Cl}_2\text{(g)} \rightarrow 2\text{FeCl}_3\text{(s)}}

    21. c) Suppose the gas used in the set up was dry hydrogen chloride gas; what would be the product obtained after the reaction? Give a reason for your answer.
    If dry hydrogen chloride gas was used, the product obtained would be Iron(II) chloride (FeCl2\text{FeCl}_2) and hydrogen gas (H2\text{H}_2).
    Reason: Chlorine gas (Cl2\text{Cl}_2) is a stronger oxidizing agent than hydrogen chloride gas (HCl\text{HCl}). Chlorine oxidizes iron to its +3 oxidation state, while hydrogen chloride oxidizes iron to its +2 oxidation state.

    Iron(II) chloride and hydrogen gas. Chlorine is a stronger oxidizing agent than hydrogen chloride.\boxed{\text{Iron(II) chloride and hydrogen gas. Chlorine is a stronger oxidizing agent than hydrogen chloride.}}

    22. a) State the Gay-Lussac's law.
    Gay-Lussac's Law of Combining Volumes states that when gases react, they do so in volumes that bear a simple whole-number ratio to one another and to the volumes of the gaseous products, provided that all volumes are measured at the same temperature and pressure.

    When gases react, they do so in volumes that bear a simple whole-number ratio to one another and to the volumes of the gaseous products, provided that all volumes are measured at the same temperature and pressure.\boxed{\text{When gases react, they do so in volumes that bear a simple whole-number ratio to one another and to the volumes of the gaseous products, provided that all volumes are measured at the same temperature and pressure.}}

    22. b) 50cm³ of Sulphur (IV) Oxide is exploded in 50cm³ of Oxygen gas. Determine the volume of the residual gas.

  7. Write the balanced chemical equation for the reaction.

    Sulphur (IV) Oxide is SO2\text{SO}_2. Oxygen gas is O2\text{O}_2. The product is Sulphur (VI) Oxide, SO3\text{SO}_3.

    2SO2(g)+O2(g)→2SO3(g)2\text{SO}_2\text{(g)} + \text{O}_2\text{(g)} \rightarrow 2\text{SO}_3\text{(g)}
  8. Determine the volume ratios from the balanced equation.

    The volume ratio of SO2:O2:SO3\text{SO}_2 : \text{O}_2 : \text{SO}_3 is 2:1:22 : 1 : 2.

  9. Identify the limiting reactant.

    Initial volumes: SO2=50 cm3\text{SO}_2 = 50 \text{ cm}^3, O2=50 cm3\text{O}_2 = 50 \text{ cm}^3.
    According to the ratio, 50 cm350 \text{ cm}^3 of SO2\text{SO}_2 would require 12×50 cm3=25 cm3\frac{1}{2} \times 50 \text{ cm}^3 = 25 \text{ cm}^3 of O2\text{O}_2.
    Since 50 cm350 \text{ cm}^3 of O2\text{O}_2 is available, O2\text{O}_2 is in excess, and SO2\text{SO}_2 is the limiting reactant.

  10. Calculate the volumes of reactants consumed and products formed.

    Volume of SO2\text{SO}_2 reacted = 50 cm350 \text{ cm}^3
    Volume of O2\text{O}_2 reacted = 25 cm325 \text{ cm}^3
    Volume of SO3\text{SO}_3 produced = 50 cm350 \text{ cm}^3 (since the ratio SO2:SO3\text{SO}_2 : \text{SO}_3 is 2:22:2)

  11. Calculate the volume of residual gas.

    Volume of unreacted O2=Initial volume of O2−Volume of O2 reacted\text{O}_2 = \text{Initial volume of O}_2 - \text{Volume of O}_2 \text{ reacted}
    Volume of unreacted O2=50 cm3−25 cm3=25 cm3\text{O}_2 = 50 \text{ cm}^3 - 25 \text{ cm}^3 = 25 \text{ cm}^3
    Residual gas consists of unreacted O2\text{O}_2 and produced SO3\text{SO}_3.
    Total volume of residual gas = Volume of unreacted O2\text{O}_2 + Volume of SO3\text{SO}_3 produced
    Total volume of residual gas = 25 cm3+50 cm3=75 cm325 \text{ cm}^3 + 50 \text{ cm}^3 = 75 \text{ cm}^3
    The volume of the residual gas is:

    75 cm3\boxed{75 \text{ cm}^3}
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