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A 2.0 imes 10⁻² ext kg ice at 0^ exto extC is dropped into a vacuum bottle originally holding 0.4 ext kg of water at 35^ exto extC. Assuming negligible heat loss or gain by the bottle, determine (a)

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here are the solutions to questions 6, 7, 8, and 9.

6. A 2.0×10−2 kg2.0 \times 10^{-2} \text{ kg} ice at 0∘C0^\circ\text{C} is dropped into a vacuum bottle originally holding 0.4 kg0.4 \text{ kg} of water at 35∘C35^\circ\text{C}. Assuming that any loss or gain of heat by the vacuum bottle is negligible, determine (a) the heat to melt the ice and (b) the final temperature after thermal equilibrium is attained.

Given constants:

  • Latent heat of fusion of ice, Lf=3.34×105 J/kgL_f = 3.34 \times 10^5 \text{ J/kg}
  • Specific heat capacity of water, cwater=4186 J/kg∘Cc_{\text{water}} = 4186 \text{ J/kg}^\circ\text{C}

Part a· 2 steps

The heat to melt the ice

  1. Use the formula for latent heat of fusion.

    The heat required to melt the ice is given by Qmelt=miceLfQ_{\text{melt}} = m_{\text{ice}} L_f.

    Qmelt=(2.0×10−2 kg)×(3.34×105 J/kg)Q_{\text{melt}} = (2.0 \times 10^{-2} \text{ kg}) \times (3.34 \times 10^5 \text{ J/kg})
  2. Calculate the heat to melt the ice.

    Qmelt=6.68×103 JQ_{\text{melt}} = 6.68 \times 10^3 \text{ J}

    The heat required to melt the ice is 6.68×103 J\boxed{6.68 \times 10^3 \text{ J}}.

Part b· 11 steps

The final temperature after thermal equilibrium is attained

  1. Set up the heat exchange equation.

    Heat gained by ice (to melt and then warm up as water) = Heat lost by initial water.
    Let TfT_f be the final equilibrium temperature.
    Heat gained by ice: Qgained=Qmelt+micecwater(Tf−0∘C)Q_{\text{gained}} = Q_{\text{melt}} + m_{\text{ice}} c_{\text{water}} (T_f - 0^\circ\text{C})
    Heat lost by water: Qlost=mwatercwater(35∘C−Tf)Q_{\text{lost}} = m_{\text{water}} c_{\text{water}} (35^\circ\text{C} - T_f)

    Qgained=QlostQ_{\text{gained}} = Q_{\text{lost}} 6.68×103 J+(2.0×10−2 kg)(4186 J/kg∘C)(Tf−0∘C)=(0.4 kg)(4186 J/kg∘C)(35∘C−Tf)6.68 \times 10^3 \text{ J} + (2.0 \times 10^{-2} \text{ kg})(4186 \text{ J/kg}^\circ\text{C})(T_f - 0^\circ\text{C}) = (0.4 \text{ kg})(4186 \text{ J/kg}^\circ\text{C})(35^\circ\text{C} - T_f)
  2. Simplify and solve for TfT_f.

    6680+83.72Tf=1674.4(35−Tf)6680 + 83.72 T_f = 1674.4 (35 - T_f) 6680+83.72Tf=58604−1674.4Tf6680 + 83.72 T_f = 58604 - 1674.4 T_f

    Combine terms with TfT_f:

    83.72Tf+1674.4Tf=58604−668083.72 T_f + 1674.4 T_f = 58604 - 6680 1758.12Tf=519241758.12 T_f = 51924 Tf=519241758.12T_f = \frac{51924}{1758.12} Tf≈29.53∘CT_f \approx 29.53^\circ\text{C}

    The final temperature after thermal equilibrium is attained is approximately 29.53∘C\boxed{29.53^\circ\text{C}}.

    7. What is the absolute temperature of boiling water and melting ice?

  3. Recall the conversion formula from Celsius to Kelvin.

    The absolute temperature (in Kelvin) is found by adding 273.15 to the Celsius temperature: TK=TC+273.15T_K = T_C + 273.15.

  4. Calculate the absolute temperature for melting ice.

    Melting ice is at 0∘C0^\circ\text{C}.

    TK=0∘C+273.15=273.15 KT_K = 0^\circ\text{C} + 273.15 = 273.15 \text{ K}
  5. Calculate the absolute temperature for boiling water.

    Boiling water is at 100∘C100^\circ\text{C}.

    TK=100∘C+273.15=373.15 KT_K = 100^\circ\text{C} + 273.15 = 373.15 \text{ K}

    The absolute temperature of melting ice is 273.15 K\boxed{273.15 \text{ K}} and boiling water is 373.15 K\boxed{373.15 \text{ K}}.

    8. Determine the temperature whose Fahrenheit and Kelvin scales have the same reading.

  6. Set up the equations for Fahrenheit and Kelvin in terms of Celsius.

    Let the temperature be xx. So, TF=xT_F = x and TK=xT_K = x.
    The conversion from Celsius to Fahrenheit is TF=95TC+32T_F = \frac{9}{5}T_C + 32.
    The conversion from Celsius to Kelvin is TK=TC+273.15T_K = T_C + 273.15, which means TC=TK−273.15T_C = T_K - 273.15.

  7. Substitute TCT_C into the Fahrenheit equation and set TF=TK=xT_F = T_K = x.

    x=95(x−273.15)+32x = \frac{9}{5}(x - 273.15) + 32
  8. Solve for xx.

    x=95x−95(273.15)+32x = \frac{9}{5}x - \frac{9}{5}(273.15) + 32 x=1.8x−491.67+32x = 1.8x - 491.67 + 32 x=1.8x−459.67x = 1.8x - 459.67

    Subtract 1.8x1.8x from both sides:

    x−1.8x=−459.67x - 1.8x = -459.67 −0.8x=−459.67-0.8x = -459.67 x=−459.67−0.8x = \frac{-459.67}{-0.8} x=574.5875x = 574.5875

    The temperature at which Fahrenheit and Kelvin scales have the same reading is approximately 574.59\boxed{574.59}.

    9. A scientist uses a γ\gamma scale for measuring temperature. In this scale water melts at 10∘γ10^\circ\gamma, and boils at 130∘γ130^\circ\gamma. The scientist measures the temperature at which sodium melts to be 127∘γ127^\circ\gamma. Express this temperature in Kelvin.

  9. Establish the relationship between the γ\gamma scale and the Kelvin scale using the reference points.

    Water melts at 0∘C0^\circ\text{C} or 273.15 K273.15 \text{ K}.
    Water boils at 100∘C100^\circ\text{C} or 373.15 K373.15 \text{ K}.
    For the γ\gamma scale: Tγ,melt=10∘γT_{\gamma, \text{melt}} = 10^\circ\gamma, Tγ,boil=130∘γT_{\gamma, \text{boil}} = 130^\circ\gamma.
    For the Kelvin scale: TK,melt=273.15 KT_{K, \text{melt}} = 273.15 \text{ K}, TK,boil=373.15 KT_{K, \text{boil}} = 373.15 \text{ K}.

    The general formula for converting between two linear temperature scales is:

    T−TlowerTupper−Tlower=constant\frac{T - T_{\text{lower}}}{T_{\text{upper}} - T_{\text{lower}}} = \text{constant}

    So, we can write:

    Tγ−Tγ,meltTγ,boil−Tγ,melt=TK−TK,meltTK,boil−TK,melt\frac{T_\gamma - T_{\gamma, \text{melt}}}{T_{\gamma, \text{boil}} - T_{\gamma, \text{melt}}} = \frac{T_K - T_{K, \text{melt}}}{T_{K, \text{boil}} - T_{K, \text{melt}}}
  10. Substitute the known values into the conversion formula.

    The temperature of sodium melting is Tγ=127∘γT_\gamma = 127^\circ\gamma.

    127−10130−10=TK−273.15373.15−273.15\frac{127 - 10}{130 - 10} = \frac{T_K - 273.15}{373.15 - 273.15} 117120=TK−273.15100\frac{117}{120} = \frac{T_K - 273.15}{100}
  11. Solve for TKT_K.

    0.975=TK−273.151000.975 = \frac{T_K - 273.15}{100}

    Multiply both sides by 100:

    97.5=TK−273.1597.5 = T_K - 273.15

    Add 273.15 to both sides:

    TK=97.5+273.15T_K = 97.5 + 273.15 TK=370.65 KT_K = 370.65 \text{ K}

    The melting temperature of sodium in Kelvin is 370.65 K\boxed{370.65 \text{ K}}.

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