Okay, Blessing, let's break down these physics problems.
Part 15b(i): Coefficient of linear expansion
Step 1: Determine the change in temperature and fractional change in length.
The temperature change is ΔT=100\circC−0\circC=100∘C.
The percentage increase in length is 0.05%, so the fractional increase in length is L0ΔL=1000.05=0.0005.
Step 2: Calculate the coefficient of linear expansion (α).
The formula for linear expansion is ΔL=αL0ΔT. Rearranging for α:
α=L0ΔTΔL=100\circC0.0005
α=0.000005/∘C
α=5.0×10−6/∘C
The coefficient of linear expansion is:
5.0×10−6/\circC
Part 15b(ii): Percentage increase of the volume of the bar
Step 1: Relate the coefficient of volume expansion (γ) to the coefficient of linear expansion (α).
For isotropic materials, the coefficient of volume expansion is approximately three times the coefficient of linear expansion:
γ=3α
γ=3×(5.0×10−6/\circC)=1.5×10−5/∘C
Step 2: Calculate the percentage increase in volume.
The fractional increase in volume is V0ΔV=γΔT.
V0ΔV=(1.5×10−5/\circC)×(100\circC)
V0ΔV=0.0015
To express this as a percentage:
Percentage increase=0.0015×100%=0.15%
The percentage increase of the volume of the bar is:
0.15%
Part 16a(i): Quantity that remains constant for thermodynamic processes
- A) Isobaric process: Pressure (P)
- B) Isochoric process: Volume (V)
- C) Isothermal process: Temperature (T)
- D) Adiabatic process: Heat exchange (Q=0)
Part 16a(ii): Show that PVγ=constant for a monatomic ideal gas undergoing an adiabatic process
Step 1: State the First Law of Thermodynamics for an adiabatic process.
For an adiabatic process, there is no heat exchange, so dQ=0.
The First Law of Thermodynamics states dQ=dU+dW.
Therefore, dU+dW=0.
Step 2: Express dU and dW for an ideal gas.
For an ideal gas, the change in internal energy is dU=nCvdT, where n is the number of moles and Cv is the molar specific heat at constant volume.
The work done by the gas is dW=PdV.
Substituting these into the equation from Step 1:
nCvdT+PdV=0(1)
Step 3: Use the ideal gas law to relate dT to dP and dV.
The ideal gas law is PV=nRT. Differentiating both sides:
PdV+VdP=nRdT
Rearranging for dT:
dT=nRPdV+VdP(2)
Step 4: Substitute dT into equation (1) and simplify.
Substitute (2) into (1):
nCv(nRPdV+VdP)+PdV=0
RCv(PdV+VdP)+PdV=0
We know that R=Cp−Cv, where Cp is the molar specific heat at constant pressure. So, Cp−CvCv(PdV+VdP)+PdV=0.
Divide by Cv:
CvCp−11(PdV+VdP)+CvPdV=0
Let γ=CvCp (the adiabatic index).
γ−11(PdV+VdP)+PdV=0
Multiply by (γ−1):
PdV+VdP+(γ−1)PdV=0
VdP+PdV+γPdV−PdV=0
VdP+γPdV=0
Step 5: Integrate the differential equation.
Divide the equation by PV:
PdP+γVdV=0
Integrate both sides:
∫PdP+γ∫VdV=∫0
lnP+γlnV=constant
lnP+lnVγ=constant
ln(PVγ)=constant
Exponentiating both sides:
PVγ=econstant
Since econstant is also a constant, we have:
PVγ=constant
Part 16b(i): Efficiency for a Carnot cycle
A) As a function of the heat that flows to and from the reservoirs:
η=1−QHQC
where QC is the heat rejected to the cold reservoir and QH is the heat absorbed from the hot reservoir.
B) As a function of the temperatures of the two reservoirs:
η=1−THTC