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Calculate the wavelength of light emitted when an electron transitions from the n=7 to n=2 energy level in a hydrogen atom using the Rydberg formula.

Physics

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Answer

D. 397.0 nm\text{D. 397.0 nm}

Step-by-step solution

5 steps

To find the wavelength of light in the Balmer series, we use the Rydberg formula:

1λ=R(1nf2−1ni2)\frac{1}{\lambda} = R \left( \frac{1}{n_f^2} - \frac{1}{n_i^2} \right)

where:

  • λ\lambda is the wavelength
  • RR is the Rydberg constant
  • nfn_f is the final principal quantum number
  • nin_i is the initial principal quantum number
  1. Identify the given values.

    For the Balmer series, the electron transitions to the nf=2n_f = 2 energy level.
    The given initial principal quantum number is ni=7n_i = 7.
    The Rydberg constant R=1.097×10−2 nm−1R = 1.097 \times 10^{-2} \text{ nm}^{-1}.

  2. Substitute the values into the Rydberg formula.

    1λ=(1.097×10−2 nm−1)(122−172)\frac{1}{\lambda} = (1.097 \times 10^{-2} \text{ nm}^{-1}) \left( \frac{1}{2^2} - \frac{1}{7^2} \right)
  3. Calculate the terms inside the parenthesis.

    1λ=(1.097×10−2 nm−1)(14−149)\frac{1}{\lambda} = (1.097 \times 10^{-2} \text{ nm}^{-1}) \left( \frac{1}{4} - \frac{1}{49} \right) 1λ=(1.097×10−2 nm−1)(0.25−0.02040816)\frac{1}{\lambda} = (1.097 \times 10^{-2} \text{ nm}^{-1}) (0.25 - 0.02040816) 1λ=(1.097×10−2 nm−1)(0.22959184)\frac{1}{\lambda} = (1.097 \times 10^{-2} \text{ nm}^{-1}) (0.22959184)
  4. Multiply by the Rydberg constant.

    1λ=0.0025187 nm−1\frac{1}{\lambda} = 0.0025187 \text{ nm}^{-1}
  5. Calculate the wavelength λ\lambda.

    λ=10.0025187 nm−1\lambda = \frac{1}{0.0025187 \text{ nm}^{-1}} λ≈397.02 nm\lambda \approx 397.02 \text{ nm}

    Comparing this value with the given options, it matches option D.

    The final answer is D. 397.0 nm\text{D. 397.0 nm}.

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