The number of atoms of chlorine present in 5.85g of NaCl is (Na=23,Cl=35.5) 2. 2.25g of an oxide of copper on reduction gave 2.00g of copper. Another oxide (2.50g) also gave 2.00g of copper. These results illustrates the law of:

Chemistry

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Answer

6.022×1022 atoms\text{6.022} \times 10^{22} \text{ atoms}

Multiple Proportions\text{Multiple Proportions}

Step-by-step solution

6 steps
  1. Step 1: Calculate the molar mass of NaCl. The atomic mass of Na is 23 g/mol. The atomic mass of Cl is 35.5 g/mol.
Molar mass of NaCl=atomic mass of Na+atomic mass of Cl\text{Molar mass of NaCl} = \text{atomic mass of Na} + \text{atomic mass of Cl} Molar mass of NaCl=23 g/mol+35.5 g/mol\text{Molar mass of NaCl} = 23 \text{ g/mol} + 35.5 \text{ g/mol} Molar mass of NaCl=58.5 g/mol\text{Molar mass of NaCl} = 58.5 \text{ g/mol}
  1. Calculate the number of moles of NaCl in 5.85 g.

    Moles of NaCl=MassMolar mass\text{Moles of NaCl} = \frac{\text{Mass}}{\text{Molar mass}} Moles of NaCl=5.85 g58.5 g/mol\text{Moles of NaCl} = \frac{5.85 \text{ g}}{58.5 \text{ g/mol}} Moles of NaCl=0.1 mol\text{Moles of NaCl} = 0.1 \text{ mol}
  2. Determine the number of moles of chlorine atoms.

    In one molecule of NaCl, there is one atom of Cl. Therefore, 0.1 mol of NaCl contains 0.1 mol of Cl atoms.

  3. Calculate the number of chlorine atoms.

    Using Avogadro's number (6.022×10236.022 \times 10^{23} atoms/mol):

    Number of Cl atoms=Moles of Cl atoms×Avogadro’s number\text{Number of Cl atoms} = \text{Moles of Cl atoms} \times \text{Avogadro's number} Number of Cl atoms=0.1 mol×6.022×1023 atoms/mol\text{Number of Cl atoms} = 0.1 \text{ mol} \times 6.022 \times 10^{23} \text{ atoms/mol} Number of Cl atoms=6.022×1022 atoms\text{Number of Cl atoms} = 6.022 \times 10^{22} \text{ atoms}

    The number of atoms of chlorine present in 5.85g of NaCl is 6.022×1022 atoms\boxed{\text{6.022} \times 10^{22} \text{ atoms}}.

    1. Step 1: Analyze the first oxide of copper. Mass of oxide = 2.25 g Mass of copper = 2.00 g Mass of oxygen = Mass of oxide - Mass of copper
    Mass of oxygen=2.25 g−2.00 g=0.25 g\text{Mass of oxygen} = 2.25 \text{ g} - 2.00 \text{ g} = 0.25 \text{ g}

    Ratio of copper to oxygen in the first oxide:

    Mass of copperMass of oxygen=2.00 g0.25 g=8\frac{\text{Mass of copper}}{\text{Mass of oxygen}} = \frac{2.00 \text{ g}}{0.25 \text{ g}} = 8
  4. Analyze the second oxide of copper.

    Mass of oxide = 2.50 g
    Mass of copper = 2.00 g
    Mass of oxygen = Mass of oxide - Mass of copper

    Mass of oxygen=2.50 g−2.00 g=0.50 g\text{Mass of oxygen} = 2.50 \text{ g} - 2.00 \text{ g} = 0.50 \text{ g}

    Ratio of copper to oxygen in the second oxide:

    Mass of copperMass of oxygen=2.00 g0.50 g=4\frac{\text{Mass of copper}}{\text{Mass of oxygen}} = \frac{2.00 \text{ g}}{0.50 \text{ g}} = 4
  5. Compare the ratios of copper to oxygen.

    For a fixed mass of copper (2.00 g), the masses of oxygen that combine with it are 0.25 g (in the first oxide) and 0.50 g (in the second oxide).
    The ratio of these masses of oxygen is:

    Mass of oxygen (second oxide)Mass of oxygen (first oxide)=0.50 g0.25 g=2\frac{\text{Mass of oxygen (second oxide)}}{\text{Mass of oxygen (first oxide)}} = \frac{0.50 \text{ g}}{0.25 \text{ g}} = 2

    This ratio (2:1) is a simple whole number.

  6. Identify the law.

    This observation illustrates the Law of Multiple Proportions. This law states that if two elements can combine to form more than one compound, then the ratios of the masses of the second element that combine with a fixed mass of the first element are ratios of small whole numbers.

    These results illustrate the law of: Multiple Proportions\boxed{\text{Multiple Proportions}}.

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